Photodissociation of o-dichlorobenzene at 266 nm | |
Zhu, RS; Zhang, H; Wang, GJ; Gu, XB; Han, KL; He, GZ; Lou, NQ | |
刊名 | chemical physics
![]() |
1999-10-01 | |
卷号 | 248期号:2-3页码:285-292 |
英文摘要 | the photodissociation o-dichlorobenzene at 266 nm has been investigated using the universal crossed molecular beam technique. photofragment translational energy distribution p(e-t) and angular distribution of photofragments have been obtained and it is estimated that 23% of the available energy is assigned to translational energy. the anisotropy parameter is determined to be 0.4. from p(e-t) and beta we deduce that o-c6h4cl2 photodissociation is a slow process. ab initio calculation has been performed and it shows that the parent molecule has a larger geometry deformation in its excited states comparing with that of the ground state. the possible dissociation mechanism has also been proposed. (c) 1999 elsevier science b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
研究领域[WOS] | chemistry ; physics |
关键词[WOS] | excited-states ; alkyl-halides ; 193 nm ; chlorobenzene ; fragment |
收录类别 | SCI |
原文出处 | true |
语种 | 英语 |
WOS记录号 | WOS:000083954300012 |
公开日期 | 2010-11-30 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/85293] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Zhu, RS,Zhang, H,Wang, GJ,et al. Photodissociation of o-dichlorobenzene at 266 nm[J]. chemical physics,1999,248(2-3):285-292. |
APA | Zhu, RS.,Zhang, H.,Wang, GJ.,Gu, XB.,Han, KL.,...&Lou, NQ.(1999).Photodissociation of o-dichlorobenzene at 266 nm.chemical physics,248(2-3),285-292. |
MLA | Zhu, RS,et al."Photodissociation of o-dichlorobenzene at 266 nm".chemical physics 248.2-3(1999):285-292. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论