RANEY©Ni Catalyzed Transfer Hydrogenation of Triacetic Acid Lactone
Xia, Chungu2; Sun, Peng2; Gao, Guang2; Zhao, Zelun1,2; Li, Fuwei2
刊名分子催化
2018
卷号32期号:3页码:205-210
关键词Biomass Triacetic Acid Lactone Transfer Hydrogenation Raney©ni
英文摘要

A catalytic transfer hydrogenation process was developed for the production of 4-hydroxy-6-methyltetrahydro-2-pyrone from biologically derived platform molecule triacetic acid lactone (TAL) under mild conditions. With isopropyl alcohol as hydrogen donor, RANEY~© Ni showed high activity with selectivity of 89% within 10 h. After 17 rounds of recycle experiments, RANEY~© Ni still exhibited good catalytic activity and it also showed high stability during TAL hydrogenation to 4-hydroxy-6-methyltetrahydro-2-pyrone in the presence of amino acid.

语种中文
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/24400]  
专题兰州化学物理研究所_OSSO国家重点实验室
通讯作者Li, Fuwei
作者单位1.University of Chinese Academy of Sciences, Beijing 100049, P. R. China
2.Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou, Gansu 730000, China
推荐引用方式
GB/T 7714
Xia, Chungu,Sun, Peng,Gao, Guang,et al. RANEY©Ni Catalyzed Transfer Hydrogenation of Triacetic Acid Lactone[J]. 分子催化,2018,32(3):205-210.
APA Xia, Chungu,Sun, Peng,Gao, Guang,Zhao, Zelun,&Li, Fuwei.(2018).RANEY©Ni Catalyzed Transfer Hydrogenation of Triacetic Acid Lactone.分子催化,32(3),205-210.
MLA Xia, Chungu,et al."RANEY©Ni Catalyzed Transfer Hydrogenation of Triacetic Acid Lactone".分子催化 32.3(2018):205-210.
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