Significantly enhancing tribological performance of epoxy by filling with ionic liquid functionalized graphene oxide | |
Zhao FY(赵福燕)2,3![]() ![]() | |
刊名 | Carbon
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2018 | |
卷号 | 136期号:0页码:309-319 |
ISSN号 | 0008-6223 |
DOI | 10.1016/j.carbon.2018.05.002 |
英文摘要 | Friction and wear of motion components operating under harsh lubrication conditions are key aspects that must be considered in vast numbers of applications. In the present work, graphene oxide (GO) functionalized in-situ with ionic liquid (IL) were uniformly dispersed into epoxy (EP) via a two-phase extraction route. In comparison to as-exfoliated GO, GO functionalized with IL (GO-IL) showed significantly improved dispersibility in EP matrix. It was disclosed that the addition of only low-loading GO-IL significantly reduced the friction and wear of EP over whole lubrication regimes, whereas as-exfoliated GO nanosheets played a positive role just under the moderate lubrication conditions. In particular, obvious synergy between the IL and GO was identified when sliding took place under harsh rubbing conditions. Comprehensive interface characterizations provided direct evidence that a nanostructured tribofilm comprising GO nanosheets, IL chemical groups and EP matrix was established. It was surmised that tribofilm growth was constantly fed by molecular species released from GO-IL reinforced EP, while GO digested within the tribofilm enhanced its robustness and improved the boundary lubrication capability. This work opens up new opportunities for formulating high-performance polymer composites for a wide range of applications subjected to harsh boundary lubrication conditions. |
学科主题 | 聚合物自润滑复合材料 |
资助项目 | 聚合物自润滑复合材料研究组 |
语种 | 英语 |
资助机构 | “National Natural Science Foundation of China” (Grant No. 51705505 ; 51475446) ; “Chinese Thousand Youth Talents Plan” Project ; the “Innovation Leading Talents” Program of Qingdao |
内容类型 | 期刊论文 |
源URL | [http://ir.licp.ac.cn/handle/362003/22995] ![]() |
专题 | 兰州化学物理研究所_固体润滑国家重点实验室 兰州化学物理研究所_先进润滑与防护材料研究发展中心 兰州化学物理研究所_青岛研发中心/青岛市资源化学与新材料研究中心 |
通讯作者 | Zhang G(张嘎) |
作者单位 | 1.University of the Chinese Academy of Sciences, Beijing 100049, China 2.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China 3.Qingdao Center of Resource Chemistry & New Materials, Qingdao 266071, China |
推荐引用方式 GB/T 7714 | Zhao FY,Zhang G,Zhang G,et al. Significantly enhancing tribological performance of epoxy by filling with ionic liquid functionalized graphene oxide[J]. Carbon,2018,136(0):309-319. |
APA | Zhao FY.,Zhang G.,Zhang G.,Qi HM.,Guo YX.,...&Zhang LG.(2018).Significantly enhancing tribological performance of epoxy by filling with ionic liquid functionalized graphene oxide.Carbon,136(0),309-319. |
MLA | Zhao FY,et al."Significantly enhancing tribological performance of epoxy by filling with ionic liquid functionalized graphene oxide".Carbon 136.0(2018):309-319. |
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