Influence of Preparation Conditions on the Performance of Ni-Based Catalysts for Glycerol Steam Reforming

doi:10.1021/acsomega.8b00860

	Influence of Preparation Conditions on the Performance of Ni-Based Catalysts for Glycerol Steam Reforming
	Xie, Shuang 1,2; Zhang, Xianghua 2; Tu, Qiang 2; Shi, Biao2 ; Cui, Yuehua2,3 ; Chen, Changguo 1
刊名	ACS OMEGA
	2018-10-01
卷号	3 期号:10 页码:13335-13342
ISSN号	2470-1343
DOI	10.1021/acsomega.8b00860
通讯作者	Cui, Yuehua(yhcui@cigit.ac.cn) ; Chen, Changguo(cgchen@cqu.edu.cn)
英文摘要	The effect of preparation conditions on the performance of Ni-based catalysts was investigated for glycerol steam reforming. La0.7Ce0.3NiO3 mixed oxides were synthesized using different solution concentrations and calcination temperatures by a co-precipitation method. Brunauer-Emmett-Teller, inductively coupled plasma, X-ray diffraction, temperature-programmed reduction, field emission scanning, electron microscopy, CO2-temperature-programmed desorption, thermal gravity analysis, and Raman spectroscopy were performed to characterize the catalysts. With an La2NiO4 phase at lowest solution concentration, a catalyst precursor included an LaNiO3 phase instead of La2NiO4 at other solution concentrations. At a low calcination temperature of 700 degrees C, it was found that the smaller particle size of CeO2 incorporated more lanthanum and higher surface basicity, and the La2O2CO3 phase could effectively inhibit and eliminate coking leading to the better performance of catalysts.
资助项目	National Natural Science Foundation of China[21473180]
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000449026500113
内容类型	期刊论文
源URL	[http://119.78.100.138/handle/2HOD01W0/7017]
专题	中国科学院重庆绿色智能技术研究院
通讯作者	Cui, Yuehua; Chen, Changguo
作者单位	1.Chongqing Univ, Coll Chem & Chem Engn, Chongqing 401331, Peoples R China 2.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100864, Peoples R China
推荐引用方式 GB/T 7714	Xie, Shuang,Zhang, Xianghua,Tu, Qiang,et al. Influence of Preparation Conditions on the Performance of Ni-Based Catalysts for Glycerol Steam Reforming[J]. ACS OMEGA,2018,3(10):13335-13342.
APA	Xie, Shuang,Zhang, Xianghua,Tu, Qiang,Shi, Biao,Cui, Yuehua,&Chen, Changguo.(2018).Influence of Preparation Conditions on the Performance of Ni-Based Catalysts for Glycerol Steam Reforming.ACS OMEGA,3(10),13335-13342.
MLA	Xie, Shuang,et al."Influence of Preparation Conditions on the Performance of Ni-Based Catalysts for Glycerol Steam Reforming".ACS OMEGA 3.10(2018):13335-13342.