Exploring BH2CN-based hydrophobic hypergolic fuels and effective fuel "additives": Imidazolylidene cyanoborane complexes

doi:10.1016/j.cclet.2017.09.036

	Exploring BH2CN-based hydrophobic hypergolic fuels and effective fuel "additives": Imidazolylidene cyanoborane complexes
	Li, XY; Nan, JY; Lu, T; Huo, HY; Zhang, YQ; Li, HB; Nie, FD; Yin, HQ; Chen, FX; Li, Xingye
刊名	CHINESE CHEMICAL LETTERS
	2018
卷号	29 期号:6 页码:939
关键词	Bipropellants ENERGETIC IONIC LIQUIDS Imidazolylidene cyanoboranes IGNITION-DELAY TIMES Hypergolic fuels ROCKET FUELS Ionic liquids BORANES Hydrophobic ANIONS FLUIDS
ISSN号	1001-8417
DOI	10.1016/j.cclet.2017.09.036
文献子类	Article
英文摘要	Two hydrophobic imidazolylidene-cyanoborane complexes were prepared by the introduction of {BH2CN} into the molecular formula via treatment of imidazolium iodide and NaBH3CN avoiding literature's tedious and hazardous procedures. These two complexes were fully characterized using IR spectroscopy, H-1 NMR and C-13 NMR spectroscopy and high-resolution mass spectrometer. The X-Ray structure of NHC-1 has been determined. NHC-2 was proved to be hypergolic with WFNA and displayed the attractive properties such as water immiscibility, wide liquid range (T-g = -22 degrees C), short ignition delay time (13 ms), high density (0.98 g/cm(3)), good density impulse (rho I-sp 347 s g cm(-3)), showing the promising application potential as a fuel and an efficient fuel additive. (C) 2017 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
WOS记录号	WOS:000436910700048
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/26710]
专题	中国科学院过程工程研究所
推荐引用方式 GB/T 7714	Li, XY,Nan, JY,Lu, T,et al. Exploring BH2CN-based hydrophobic hypergolic fuels and effective fuel "additives": Imidazolylidene cyanoborane complexes[J]. CHINESE CHEMICAL LETTERS,2018,29(6):939, 941.
APA	Li, XY.,Nan, JY.,Lu, T.,Huo, HY.,Zhang, YQ.,...&Chen, Fu-Xue.(2018).Exploring BH2CN-based hydrophobic hypergolic fuels and effective fuel "additives": Imidazolylidene cyanoborane complexes.CHINESE CHEMICAL LETTERS,29(6),939.
MLA	Li, XY,et al."Exploring BH2CN-based hydrophobic hypergolic fuels and effective fuel "additives": Imidazolylidene cyanoborane complexes".CHINESE CHEMICAL LETTERS 29.6(2018):939.