Oxidative carbonylation of aniline over a polymer-supported palladium-copper catalyst
Wan, BS; Liao, SJ; Yu, DR
刊名reactive & functional polymers
2000-08-01
卷号45期号:1页码:55-59
关键词polymer-supported bimetallic catalyst oxidative carbonylation ethyl N-phenylcarbamate synergic effect
英文摘要the polymer-supported bimetallic catalyst fvp-pdcl2-2cucl(2) (pvp, poly(n-vinyl-2-pyrrolidone), obtained in situ by the addition of cucl2 to an alcoholic solution of pvp-pdcl2, exhibits high selectivity and activity for the oxidative carbonylation of aniline with carbon monoxide and oxygen to ethyl n-phenylcarbamate in the presence of a base (naoac) under atmospheric pressure. the strong synergic effect of pd-cu gives rise to a clear increase in the selectivity and activity. (c) 2000 elsevier science b.v. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, applied ; engineering, chemical ; polymer science
研究领域[WOS]chemistry ; engineering ; polymer science
关键词[WOS]homogeneous multimetallic catalysts ; ruthenium bimetallic catalysts ; carbon-monoxide ; mild conditions ; carbamate esters ; sodium hydride ; complexes ; olefins ; halides ; amines
收录类别SCI
原文出处true
语种英语
WOS记录号WOS:000088941500007
公开日期2010-11-30
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/84801]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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Wan, BS,Liao, SJ,Yu, DR. Oxidative carbonylation of aniline over a polymer-supported palladium-copper catalyst[J]. reactive & functional polymers,2000,45(1):55-59.
APA Wan, BS,Liao, SJ,&Yu, DR.(2000).Oxidative carbonylation of aniline over a polymer-supported palladium-copper catalyst.reactive & functional polymers,45(1),55-59.
MLA Wan, BS,et al."Oxidative carbonylation of aniline over a polymer-supported palladium-copper catalyst".reactive & functional polymers 45.1(2000):55-59.
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