Liquid-liquid extraction separation of lithium isotopes by using room-temperature ionic liquids-chloroform mixed solvent system contained benzo-15-crown-5

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	Liquid-liquid extraction separation of lithium isotopes by using room-temperature ionic liquids-chloroform mixed solvent system contained benzo-15-crown-5
	Xiao, Jiang 1,2; Jia, Yongzhong 1; Shi, Chenglong 1; Wang, Xingquan 1; Yao, Ying 1; Jing, Yan 1
刊名	JOURNAL OF MOLECULAR LIQUIDS
	2016-11-01
卷号	223 页码:1032-1038
关键词	Lithium Isotopes Separation Solvent Extraction Ionic Liquid Benzo-15-crown-5 Separation Factor
文献子类	Article
英文摘要	A novel liquid-liquid extraction system was investigated for the selective separation of lithium isotopes using ionic liquids.(ILs = [C(6,8,10,12)mim](+)[PF6](-)) as extraction solvent and benzo-15-crown-5 (B15C5) as extractant. The effects of the concentration of lithium salt, counter anion of lithium salt, initial pH of aqueous phase, and extraction temperature on the lithium isotopes separation were studied. The maximum single-stage separation factor alpha of Li-6/Li-7 obtained in the present study was 1.038 +/- 0.002, indicating the lighter isotope Li-6 was enriched in organic phase while the heavier isotope Li-7 was concentrated in the aqueous phase. The formation of 2:1 complex Li(B15C5)(2)(+) in the IL phase was determined on the basis of slope analysis method. The large value of the free energy change (-G(0) = 77.87J mol(-1)) indicated the high separation capability of the lithium isotopes by B15C5/30%CH3Cl-70% C(6)mimPF(6) mixture extraction system. Lithium in Li(B15C5)(2)(+) complex was stripped by 0.5 mol center dot L-1 HCl solution. The extraction system offers high efficiency, simplicity application prospect to separation lithium isotope separation from LiCl solution. (c) 2016 Elsevier B.V. All rights reserved.
WOS关键词	MONOBENZO-15-CROWN-5 RESIN ; CROWN-ETHERS ; BASES HSAB ; SOFT ACIDS ; CHROMATOGRAPHY ; STRATEGY ; AMALGAM ; GREEN ; HARD
WOS研究方向	Chemistry ; Physics
语种	英语
WOS记录号	WOS:000386986300124
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/6360]
专题	青海盐湖研究所_青海盐湖研究所知识仓储青海盐湖研究所_盐湖资源综合利用工程技术中心
作者单位	1.Chinese Acad Sience, Qinghai Inst Salt Lakes, Key Lab Compehens & Highly Uitilzat Salt Lakes Re, Xining 810008, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Xiao, Jiang,Jia, Yongzhong,Shi, Chenglong,et al. Liquid-liquid extraction separation of lithium isotopes by using room-temperature ionic liquids-chloroform mixed solvent system contained benzo-15-crown-5[J]. JOURNAL OF MOLECULAR LIQUIDS,2016,223:1032-1038.
APA	Xiao, Jiang,Jia, Yongzhong,Shi, Chenglong,Wang, Xingquan,Yao, Ying,&Jing, Yan.(2016).Liquid-liquid extraction separation of lithium isotopes by using room-temperature ionic liquids-chloroform mixed solvent system contained benzo-15-crown-5.JOURNAL OF MOLECULAR LIQUIDS,223,1032-1038.
MLA	Xiao, Jiang,et al."Liquid-liquid extraction separation of lithium isotopes by using room-temperature ionic liquids-chloroform mixed solvent system contained benzo-15-crown-5".JOURNAL OF MOLECULAR LIQUIDS 223(2016):1032-1038.