Solubility Phase Diagram of the Ca(NO3)(2)-LiNO3-H2O System

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	Solubility Phase Diagram of the Ca(NO3)(2)-LiNO3-H2O System
	Jiang, Juan 1; Yin, Xia 1; Li, Dongdong 2; Tan, Yuqi 1; Zeng, Dewen 3
刊名	JOURNAL OF CHEMICAL AND ENGINEERING DATA
	2016-03-01
卷号	61 期号:3 页码:1125-1130
文献子类	Article
英文摘要	Solubility isotherms of the ternary Ca(NO3)(2)-LiNO3-H2O system were elab-orately determined at T = (273.15, 298.15, and 323.15 K) by an isothermal equilibrium method, and the results showed that there are two stable solubility branches for the solid phases Ca(NO3)(2)center dot 4H(2)O and LiNO3 center dot 3H(2)O at 273.15 K, and four stable solubility isotherms for the solid phases Ca(NO3)(2)center dot 4H(2)O, Ca(NO3)(2)center dot 3H(2)O, LiNO3 center dot 3H(2)O, and LiNO3 at 298.15 K, and solubility data corresponding to solid phases Ca(NO3)(2)center dot 3H(2)O, Ca(NO3)(2)center dot 2H(2)O, and LiNO3 at 323.15 K. The experimental data were correlated by a modified Brunauer-Emmett-Teller (BET) model, to obtain the complete phase diagram of the ternary system over the temperature range from 273 to 373 K. On the basis of the simulated polytherms, an eutectic point Ca(NO3)(2)center dot 4H(2)O + LiNO3 center dot 3H(2)O was recognized, and the melting temperature and fusion heat are 290.5 K and 139.8 J-g(-1), respectively, measured by differential scanning calorimetry.
WOS关键词	CONCENTRATED-SOLUTIONS ; WATER ACTIVITIES ; ELECTROLYTE ; PREDICTION ; (LICL
WOS研究方向	Thermodynamics ; Chemistry ; Engineering
语种	英语
WOS记录号	WOS:000372043600012
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/6306]
专题	青海盐湖研究所_青海盐湖研究所知识仓储
作者单位	1.Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Peoples R China 3.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
推荐引用方式 GB/T 7714	Jiang, Juan,Yin, Xia,Li, Dongdong,et al. Solubility Phase Diagram of the Ca(NO3)(2)-LiNO3-H2O System[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2016,61(3):1125-1130.
APA	Jiang, Juan,Yin, Xia,Li, Dongdong,Tan, Yuqi,&Zeng, Dewen.(2016).Solubility Phase Diagram of the Ca(NO3)(2)-LiNO3-H2O System.JOURNAL OF CHEMICAL AND ENGINEERING DATA,61(3),1125-1130.
MLA	Jiang, Juan,et al."Solubility Phase Diagram of the Ca(NO3)(2)-LiNO3-H2O System".JOURNAL OF CHEMICAL AND ENGINEERING DATA 61.3(2016):1125-1130.