A multifunctional polymeric nanofilm with robust chemical performances for special wettability | |
Wang, Yabin1,2; Lin, Feng1; Dong, Yaping1; Liu, Zhong1; Li, Wu1; Huang, Yudong2 | |
刊名 | NANOSCALE
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2016 | |
卷号 | 8期号:9页码:5153-5161 |
文献子类 | Article |
英文摘要 | A multifunctional polymeric nanofilm of a triazinedithiolsilane compound, which can protect metallic substrates and activate the corresponding surface simultaneously, is introduced onto a copper mesh surface via facile solution-immersion approaches. The resultant interface exhibits hydrophilic features due to the existence of silanol groups (SiOH) outward and has the potential to act as a superhydrophilic and underwater superoleophobic material. As the polymeric nanofilm atop the copper mesh is modified with long-chain octadecyltrichlorosilane (OTS), the functionalized surface becomes superhydrophobic and superoleophilic. The OTS-modified polymeric nanofilm shows outstanding chemical durability and stability that are seldom concurrently satisfied for a material with special wettability, owing to its inherent architecture. These textures generate high separation efficiency, durable separation capability and excellent thermal stability. The protective ability, originating from the textures of the underlying cross-linked disulfide units (-SS-) and siloxane networks (SiOSi) on the top of the nanofilm, prolongs the chemical durability. The activating capability stemming from the residual SiOH groups improves the chemical stability as a result of the chemical bonds developed by these sites. The significant point of this investigation lies in enlightening us on the fabrication of multifunctional polymeric nanofilms on different metal surfaces using various triazinedithiolsilane compounds, and on the construction of interfaces with controllable wettable performances in demanding research or industrial applications. |
WOS关键词 | OIL-WATER SEPARATION ; OIL/WATER SEPARATION ; SUPERHYDROPHOBIC SURFACES ; COATED MESH ; COPPER ; FABRICATION ; CORROSION ; SUPEROLEOPHOBICITY ; FUNCTIONALIZATION ; NANOSTRUCTURES |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
语种 | 英语 |
WOS记录号 | WOS:000371479000041 |
内容类型 | 期刊论文 |
源URL | [http://ir.isl.ac.cn/handle/363002/6305] ![]() |
专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源综合利用工程技术中心 青海盐湖研究所_盐湖资源与化学实验室 |
作者单位 | 1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Qinghai, Peoples R China 2.Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Yabin,Lin, Feng,Dong, Yaping,et al. A multifunctional polymeric nanofilm with robust chemical performances for special wettability[J]. NANOSCALE,2016,8(9):5153-5161. |
APA | Wang, Yabin,Lin, Feng,Dong, Yaping,Liu, Zhong,Li, Wu,&Huang, Yudong.(2016).A multifunctional polymeric nanofilm with robust chemical performances for special wettability.NANOSCALE,8(9),5153-5161. |
MLA | Wang, Yabin,et al."A multifunctional polymeric nanofilm with robust chemical performances for special wettability".NANOSCALE 8.9(2016):5153-5161. |
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