Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone

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	Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone
	Zhao, Jing-Jing 1; Pei, Hao 1; Chen, Yan-Mei 1,2; Lu, Ning 1; Liu, Jin-Na 1; Hu, Jin-Fa 1; Liu, Wei 1; Li, Wu 2; Li, Yahong 1
刊名	ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
	2015-06-01
卷号	641 期号:7 页码:1322-1328
关键词	Hydroamination Titanium Ring-opening Polymerization E-caprolactone
文献子类	Article
英文摘要	The ligands 2-pyrazol-1-yl-1H-indole (HL1) and 2-1,2,4-triazol-1-yl-1H-indole (HL2) individually reacted with Ti(NMe2)(4) in tetrahydrofuran to form the corresponding complexes Ti(L1)(2)(NMe2)(2) (1) and Ti(L2)(2)(NMe2)(2) (2), respectively. The titanium complexes were fully characterized by NMR measurement and elemental analysis as well as the single-crystal X-ray diffraction of 1 and 2. Both 1 and 2 exhibit high activities towards intermolecular hydroamination of terminal alkynes with high selectivity, and they also efficiently promote the ring-opening polymerization of E-caprolactone.
WOS关键词	INTRAMOLECULAR ALKENE HYDROAMINATION ; INTERMOLECULAR ALKYNE HYDROAMINATION ; N BOND FORMATION ; TITANIUM COMPLEXES ; C-N ; ALPHA,BETA-UNSATURATED IMINES ; ASYMMETRIC HYDROAMINATION ; AMIDATE COMPLEXES ; TERMINAL ALKYNES ; ZIRCONIUM
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000356722400023
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/6146]
专题	青海盐湖研究所_青海盐湖研究所知识仓储青海盐湖研究所_盐湖资源综合利用工程技术中心
作者单位	1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Jing-Jing,Pei, Hao,Chen, Yan-Mei,et al. Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2015,641(7):1322-1328.
APA	Zhao, Jing-Jing.,Pei, Hao.,Chen, Yan-Mei.,Lu, Ning.,Liu, Jin-Na.,...&Li, Yahong.(2015).Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,641(7),1322-1328.
MLA	Zhao, Jing-Jing,et al."Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 641.7(2015):1322-1328.