Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K

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	Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K
	Jiang, YC ; Gao, SY ; Xia, SP ; Wang, JJ ; Zhuo, KL ; Hu, MC
刊名	JOURNAL OF THE CHINESE CHEMICAL SOCIETY
	2003-10-01
卷号	50 期号:5 页码:947-952
关键词	Density Apparent Molar Volume Standard Transfer Volume Volumetric Interaction Parameter Cscl Saccharide
文献子类	Article
英文摘要	Densities have been measured for the CsCl-saccharide (D-glucose, D-fructose)-water systems at 298.15 K. These data were used to calculate the apparent molar volume of CsCl ( V-Phi,V-E) and the saccharides (V-Phi,V-S), and the infinite dilution apparent molar volume V-Phi,E(0) and V-Phi,S(0) in the studied solutions. In addition, the standard transfer volume Delta(t)V(phi,E)(0) of CsCl from water to aqueous saccharides solutions, and Delta(t)V(phi,S)(0) of saccharides from water to CsCl solutions have been evaluated and discussed using the structural interaction model. The volumetric interaction parameters for CsCl with saccharide in water were obtained and analyzed by the group additivity principle and the stereochemistry of the saccharide molecules.
WOS关键词	APPARENT MOLAR VOLUMES ; AQUEOUS-SOLUTIONS ; HEAT-CAPACITIES ; STEREOCHEMICAL ASPECTS ; EXCESS-ENTHALPIES ; WATER ; HYDRATION ; SUGARS ; MONOSACCHARIDES ; THERMODYNAMICS
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000186578700002
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/6097]
专题	青海盐湖研究所_青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China 2.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Shaanxi, Peoples R China 3.Henan Normal Univ, Sch Chem & Environm Sci, Xinxiang 453002, Henan, Peoples R China
推荐引用方式 GB/T 7714	Jiang, YC,Gao, SY,Xia, SP,et al. Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K[J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY,2003,50(5):947-952.
APA	Jiang, YC,Gao, SY,Xia, SP,Wang, JJ,Zhuo, KL,&Hu, MC.(2003).Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K.JOURNAL OF THE CHINESE CHEMICAL SOCIETY,50(5),947-952.
MLA	Jiang, YC,et al."Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K".JOURNAL OF THE CHINESE CHEMICAL SOCIETY 50.5(2003):947-952.