Synthesis, Structural Characterization, and Catalytic Activity of Scandium, Samarium, and Dysprosium Complexes Supported by Tris(pyrrolyl-alpha-methyl)amine Ligand

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	Synthesis, Structural Characterization, and Catalytic Activity of Scandium, Samarium, and Dysprosium Complexes Supported by Tris(pyrrolyl-alpha-methyl)amine Ligand
	Zhou, Fengying 1; Wu, Jing 1; Lin, Miaoshui 1; Zhao, Yang 1; Wu, Jian 1; Zhang, Yong 1; Li, Wu 2; Li, Yahong 1,2,3
刊名	ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
	2011
卷号	637 期号:1 页码:117-121
关键词	Scandium Samarium Dysprosium Polymerization Epsilon-caprolactone
文献子类	Article
英文摘要	The synthesis, structures and catalytic activities of three organolanthanide complexes supported by the H(3)tpa ligand (H(3)tpa = tris(pyrrolyl-alpha-methyl) amine) are described. Treatment of H(3)tpa with one equivalent of Ln[N(SiMe3)(2)](3) (Ln = Sc, Sm, Dy) in THF gives, after recrystallization from toluene/THF solution, Sc(tpa)(THF)(2) (1), Sm(tpa)(THF)(3) (2) and Dy(tpa)(THF)(3) (3) in good yields. The structures of complexes 1-3 were determined by single-crystal X-ray diffraction and elemental analysis. Complexes 2 and 3 exhibited good catalytic activity for the polymerization of epsilon-caprolactone.
WOS关键词	POLYBENZIMIDAZOLE TRIPODAL LIGANDS ; ORGANOLANTHANIDE COMPLEXES ; LANTHANIDE COMPLEXES ; EPSILON-CAPROLACTONE ; POLYMERIZATION CATALYSIS ; ALKYL COMPLEXES ; REACTIVITY ; REDUCTION ; COORDINATION ; CHEMISTRY
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000285788600021
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/5978]
专题	青海盐湖研究所_青海盐湖研究所知识仓储青海盐湖研究所_盐湖资源综合利用工程技术中心
作者单位	1.Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Fengying,Wu, Jing,Lin, Miaoshui,et al. Synthesis, Structural Characterization, and Catalytic Activity of Scandium, Samarium, and Dysprosium Complexes Supported by Tris(pyrrolyl-alpha-methyl)amine Ligand[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2011,637(1):117-121.
APA	Zhou, Fengying.,Wu, Jing.,Lin, Miaoshui.,Zhao, Yang.,Wu, Jian.,...&Li, Yahong.(2011).Synthesis, Structural Characterization, and Catalytic Activity of Scandium, Samarium, and Dysprosium Complexes Supported by Tris(pyrrolyl-alpha-methyl)amine Ligand.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,637(1),117-121.
MLA	Zhou, Fengying,et al."Synthesis, Structural Characterization, and Catalytic Activity of Scandium, Samarium, and Dysprosium Complexes Supported by Tris(pyrrolyl-alpha-methyl)amine Ligand".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 637.1(2011):117-121.