Structure of aqueous potassium metaborate solution

CORC > 青海盐湖研究所 > 中国科学院青海盐湖研究所 > 青海盐湖研究所知识仓储

	Structure of aqueous potassium metaborate solution
	Zhu, F. Y.1; Fang, C. H.1; Fang, Y.1; Zhou, Y. Q.1; Ge, H. W.1; Liu, H. Y.1,2
刊名	JOURNAL OF MOLECULAR STRUCTURE
	2014-07-24
卷号	1070 页码:80-85
关键词	Potassium Metaborate Solution Structure X-ray Scattering Raman Spectra
文献子类	Article
英文摘要	The structure of aqueous potassium metaborate solutions has been confirmed by X-ray scattering, Raman spectra and species distribution calculation. The optimized structure of B(OH)(4)(-) was obtained by density functional theory calculation. The hydration distance and hydration number of K+ in aqueous potassium metaborate solution were given by X-ray scattering. The B-O(H2O) distance in hydrated anion B(OH)(4)(-) were determined to be 0.37 nm with the hydration number of 2.3 per hydroxyl(-OH). The K-B distance of the contact ions KB(OH)(4)(0) was measured to be 0.34 nm. (C) 2014 Elsevier B.V. All rights reserved.
WOS关键词	HYDRATED OXYSALT MINERALS ; BOND-VALENCE APPROACH ; BORIC ACID ; SODIUM PENTABORATE ; EQUILIBRIUM STEPS ; CRYSTAL-STRUCTURE ; BORATE MINERALS ; WATER ; PARAGENESIS ; POLYANIONS
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000337884900012
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/5734]
专题	青海盐湖研究所_青海盐湖研究所知识仓储青海盐湖研究所_盐湖资源与化学实验室中国科学院青海盐湖研究所
作者单位	1.Chinese Acad Sci, Inst Salt Lakes, Key Lab Salt Resources & Chem, Xining 8100084, Qinghai, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhu, F. Y.,Fang, C. H.,Fang, Y.,et al. Structure of aqueous potassium metaborate solution[J]. JOURNAL OF MOLECULAR STRUCTURE,2014,1070:80-85.
APA	Zhu, F. Y.,Fang, C. H.,Fang, Y.,Zhou, Y. Q.,Ge, H. W.,&Liu, H. Y..(2014).Structure of aqueous potassium metaborate solution.JOURNAL OF MOLECULAR STRUCTURE,1070,80-85.
MLA	Zhu, F. Y.,et al."Structure of aqueous potassium metaborate solution".JOURNAL OF MOLECULAR STRUCTURE 1070(2014):80-85.