Isopiestic Measurement and Solubility Evaluation of the Ternary System LiCl-SrCl2-H2O at 298.15 K
Guo, Lijiang1; Sun, Bai1; Zeng, Dewen1,2; Yao, Yan1; Han, Haijun1
刊名JOURNAL OF CHEMICAL AND ENGINEERING DATA
2012-03-01
卷号57期号:3页码:817-827
文献子类Article
英文摘要Water activity in the ternary system LiCl-SrCl2-H2O and its sub-binary systems has been elaborately measured by the isopiestic method. The measured water activities were used to justify the reliability of solubility isotherms reported in literature by correlating them with two thermodynamic models, that is, the extended Pitzer model and the Pitzer-Simonson-Clegg model. It was found that the extended Pitzer model cannot correlate consistently the water activities measured and either set of the solubility isotherms reported in literature for this concerned system, no matter how its parameters were adjusted. However, the Pitzer-Simonson-Clegg model can correlate consistently our measured water activities and the solubility isotherms reported by the literature (Kydynov et al. Issled. Obl. Khim. Tekhnol. Miner. Solei Okislov 1965, 146-150), which should be more reliable than solubility data reported in other references.
WOS关键词ION-INTERACTION MODEL ; ACTIVITY-COEFFICIENTS ; OSMOTIC COEFFICIENTS ; STRONTIUM CHLORIDE ; AQUEOUS-SOLUTIONS ; THERMODYNAMICS ; 25-DEGREES-C ; MIXTURES ; MULTICOMPONENT ; REPRESENTATION
WOS研究方向Chemistry ; Engineering
语种英语
WOS记录号WOS:000301169900021
内容类型期刊论文
源URL[http://ir.isl.ac.cn/handle/363002/5647]  
专题青海盐湖研究所_青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
2.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
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Guo, Lijiang,Sun, Bai,Zeng, Dewen,et al. Isopiestic Measurement and Solubility Evaluation of the Ternary System LiCl-SrCl2-H2O at 298.15 K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2012,57(3):817-827.
APA Guo, Lijiang,Sun, Bai,Zeng, Dewen,Yao, Yan,&Han, Haijun.(2012).Isopiestic Measurement and Solubility Evaluation of the Ternary System LiCl-SrCl2-H2O at 298.15 K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,57(3),817-827.
MLA Guo, Lijiang,et al."Isopiestic Measurement and Solubility Evaluation of the Ternary System LiCl-SrCl2-H2O at 298.15 K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 57.3(2012):817-827.
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