A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures

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	A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures
	Zhang, Suyun 1; Chen, Wenqian 1; Hu, Bin 2; Chen, Yanmei 1; Zheng, Lina 1; Li, Yahong 1,3; Li, Wu 2
刊名	JOURNAL OF COORDINATION CHEMISTRY
	2012
卷号	65 期号:23 页码:4147-4155
关键词	Tetranuclear Cubane-like Nickel Copper
文献子类	Article
英文摘要	A tetranuclear cubane-like cluster [Ni-4(HL)(4)(DMSO)(2)] center dot 2DMSO center dot H2O (1) and a dinuclear compound [Cu2Cl2(H2L)(2)] center dot 1.5MeOH (2) (H3L = 3-(2-hydroxy-benzylideneamino)propane-1,2-diol) have been prepared and characterized by X-ray single crystal diffraction, IR, and elemental analysis. The X-ray diffraction analysis indicated that the four metals of 1 showed a Ni4O4 cubane arrangement, and two of the six faces of the Ni4O4 cubane were capped by DMSO. Complex 1 is the first reported DMSO capped Ni4O4 cubane cluster. Complex 2 contains a u(2)-Cl bridged dinuclear core with each Cu-II ion exhibiting pseudo square pyramidal geometry.
WOS关键词	SINGLE-CHAIN MAGNETS ; SPIN CLUSTERS ; NI-II ; POLYNUCLEAR ; GENERATION ; BEHAVIOR ; FAMILY ; ANION
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000310309500009
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/5643]
专题	青海盐湖研究所_青海盐湖研究所知识仓储青海盐湖研究所_盐湖资源与化学实验室中国科学院青海盐湖研究所
作者单位	1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 73000, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Suyun,Chen, Wenqian,Hu, Bin,et al. A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures[J]. JOURNAL OF COORDINATION CHEMISTRY,2012,65(23):4147-4155.
APA	Zhang, Suyun.,Chen, Wenqian.,Hu, Bin.,Chen, Yanmei.,Zheng, Lina.,...&Li, Wu.(2012).A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures.JOURNAL OF COORDINATION CHEMISTRY,65(23),4147-4155.
MLA	Zhang, Suyun,et al."A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures".JOURNAL OF COORDINATION CHEMISTRY 65.23(2012):4147-4155.