Effective elimination of isobaric ions interference and precise thermal ionization mass spectrometer analysis for boron isotope

CORC > 青海盐湖研究所 > 中国科学院青海盐湖研究所 > 青海盐湖研究所知识仓储

	Effective elimination of isobaric ions interference and precise thermal ionization mass spectrometer analysis for boron isotope
	Wei, HZ ; Xiao, YK ; Sun, A ; Zhang, CG ; Li, SZ
刊名	INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
	2004-07-01
卷号	235 期号:2 页码:187-195
关键词	Boron Isotopes Isobaric Ions Interference Ionization Depressor Thermal Ionization Mass Spectrometer
文献子类	Article
英文摘要	An ionization depressor, 1% H3PO4 was used to eliminate the isobaric interference that has been of a great concern during the procedure of boron isotopic ratio analysis by thermal ionization mass spectrometer (TIMS). Our experiments have shown that it appears to be an effective method to completely restrain the formation of isobaric ions of CNO- and Cs2CNO+ in the ionization source of mass spectrometer. We have also discussed the optimum proportion of depressor to nitrite for precise analysis of boron isotopes in natural samples based on a conditional experiment. In this case, the pretreatment of boron extraction from natural samples is greatly simplified since it is not necessary to remove nitrite and organic matter completely. In virtue of the method, we determined boron isotope in different types of natural samples, and our results are consistent with previous reports. (C) 2004 Elsevier B.V. All rights reserved.
WOS关键词	BORATE DEPOSIT ; SEPARATION ; VOLATILIZATION ; GEOCHEMISTRY ; EVAPORATION ; EXCHANGE ; SAMPLES ; COMPLEX ; WATERS ; ACID
WOS研究方向	Physics ; Spectroscopy
语种	英语
WOS记录号	WOS:000222441300011
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/5611]
专题	青海盐湖研究所_青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Wei, HZ,Xiao, YK,Sun, A,et al. Effective elimination of isobaric ions interference and precise thermal ionization mass spectrometer analysis for boron isotope[J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY,2004,235(2):187-195.
APA	Wei, HZ,Xiao, YK,Sun, A,Zhang, CG,&Li, SZ.(2004).Effective elimination of isobaric ions interference and precise thermal ionization mass spectrometer analysis for boron isotope.INTERNATIONAL JOURNAL OF MASS SPECTROMETRY,235(2),187-195.
MLA	Wei, HZ,et al."Effective elimination of isobaric ions interference and precise thermal ionization mass spectrometer analysis for boron isotope".INTERNATIONAL JOURNAL OF MASS SPECTROMETRY 235.2(2004):187-195.