Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water

doi:10.3390/catal8050193

	Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water
	Li, Yaru 1,2; Guo, Xingcui 2; Liu, Daosheng 1; Mu, Xindong 2; Chen, Xiufang 2; Shi, Yan 1
刊名	CATALYSTS
	2018-05-01
卷号	8 期号:5
关键词	Furfural Co-ni Catalyst Cyclopentanone Cyclopentanol Hydrogenation
ISSN号	2073-4344
DOI	10.3390/catal8050193
文献子类	Article
英文摘要	Co-Ni catalysts, prepared by a typical wetness impregnation method, can selectively convert furfural (FFA) to cyclopentanone (CPO) or cyclopentanol (CPL) in water, respectively. The catalytic performance depends strongly on the support. It is also strongly influenced by the Co-Ni loadings of the catalyst. The 10%Co-10%Ni/TiO2 catalyst showed the highest selectivity toward CPO (53.3%) with almost complete FFA conversion, and the main product was CPL (45.4%) over 20%Co/TiO2 at the optimized conditions (150 degrees C, 4 MPa H-2, 4 h). The surface morphology, surface area, composition and reducibility properties of these catalysts were fully characterized by XRD, H-2-TPR, ICP-AES and SEM. The factors that influenced the activity of catalysts were also investigated in detail. Additionally, the stability of catalyst for the hydrogenative rearrangement of FFA was studied.
WOS关键词	BIMETALLIC CATALYSTS ; COBALT CATALYSTS ; SUPPORTED COBALT ; CARBON ; HYDROGENATION ; CHEMICALS ; TRANSFORMATION ; REARRANGEMENT ; NANOTUBES ; COMPOUND
WOS研究方向	Chemistry
语种	英语
出版者	MDPI
WOS记录号	WOS:000435191500022
资助机构	National Natural Science Foundation of China(21433001 ; key basic research project of Shandong Natural Science Foundation(ZR201708240147) ; Young Taishan Scholars Program of Shandong Province(tsqn 20161052) ; 21406251)
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/11377]
专题	中国科学院青岛生物能源与过程研究所
通讯作者	Guo, Xingcui; Shi, Yan
作者单位	1.Liaoning Shihua Univ, Coll Chem Chem Engn & Environm Engn, 1 Dandong Rd, Fushun 113001, Liaoning, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Li, Yaru,Guo, Xingcui,Liu, Daosheng,et al. Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water[J]. CATALYSTS,2018,8(5).
APA	Li, Yaru,Guo, Xingcui,Liu, Daosheng,Mu, Xindong,Chen, Xiufang,&Shi, Yan.(2018).Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water.CATALYSTS,8(5).
MLA	Li, Yaru,et al."Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water".CATALYSTS 8.5(2018).