Pd@Zn-MOF-74: Restricting a Guest Molecule by the Open-Metal Site in a Metal-Organic Framework for Selective Semihydrogenation

doi:10.1021/acs.inorgchem.8b01652

	Pd@Zn-MOF-74: Restricting a Guest Molecule by the Open-Metal Site in a Metal-Organic Framework for Selective Semihydrogenation
	Luo, Feng 2; Yin, Wen Hui 2; Yang, Li Xiao 2; Tao, Yuan 2; Zheng, An Min 1; Li, Jian Qiang 2; Huang, Ling 1; Qiong, Hui 2
刊名	INORGANIC CHEMISTRY
	2018-10-15
卷号	57 期号:20 页码:12444-12447
ISSN号	0020-1669
DOI	10.1021/acs.inorgchem.8b01652
英文摘要	In this work, we found that the open-metal site in a metal-organic framework (MOF) can be used to enhance such selectivity. Hydrogenation of phenyl acetylene over such a catalyst enables ultrahigh styrene selectivity of 92% at full conversion with a turnover frequency of 98.1 h(-1). The origin of ultrahigh selectivity, as unveiled by density functional theory calculation, is due to a coordination interaction between the open Zn(II) site and the C C bond of phenylacetylene.
资助项目	NSF of China[21871047] ; NSF of China[21661001] ; NSF of China[21661002]
WOS关键词	CATALYST ; HYDROGENATION ; ALKYNES ; PERFORMANCE ; GA
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000447680400002
资助机构	NSF of China ; NSF of China ; NSF of China ; NSF of China ; NSF of China ; NSF of China ; NSF of China ; NSF of China
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/13240]
专题	中国科学院武汉物理与数学研究所
通讯作者	Luo, Feng; Zheng, An Min
作者单位	1.Chinese Acad Sci, Natl Ctr Magnet Resonance Wuhan, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Hubei, Peoples R China 2.East China Univ Technol, Sch Biol Chem & Mat Sci, State Key Lab Nucl Resources & Environm, Nanchang 344000, Jiangxi, Peoples R China
推荐引用方式 GB/T 7714	Luo, Feng,Yin, Wen Hui,Yang, Li Xiao,et al. Pd@Zn-MOF-74: Restricting a Guest Molecule by the Open-Metal Site in a Metal-Organic Framework for Selective Semihydrogenation[J]. INORGANIC CHEMISTRY,2018,57(20):12444-12447.
APA	Luo, Feng.,Yin, Wen Hui.,Yang, Li Xiao.,Tao, Yuan.,Zheng, An Min.,...&Qiong, Hui.(2018).Pd@Zn-MOF-74: Restricting a Guest Molecule by the Open-Metal Site in a Metal-Organic Framework for Selective Semihydrogenation.INORGANIC CHEMISTRY,57(20),12444-12447.
MLA	Luo, Feng,et al."Pd@Zn-MOF-74: Restricting a Guest Molecule by the Open-Metal Site in a Metal-Organic Framework for Selective Semihydrogenation".INORGANIC CHEMISTRY 57.20(2018):12444-12447.