Recyclable bio-based crosslinked polyurethanes with self-healing ability | |
Wu, Qing-Yun; Gu, Lin | |
刊名 | JOURNAL OF APPLIED POLYMER SCIENCE |
2018 | |
卷号 | 135期号:21 |
关键词 | Diels-alder Reaction Shape-memory Behavior Poly(Lactic Acid) Body-temperature Chain Extenders Epoxy Monomer Polymers Elastomers Polyols Resistance |
英文摘要 | We report the synthesis of a linear bio-based polyurethane (bio-PU) containing furan ring by using renewable polylactide copolymer diol and 2,5-furandimethanol as a soft segment and chain extender, respectively, in which the reversible crosslinked covalent bonds between hard segments were incorporated via Diels-Alder (D-A) reaction between the furan ring of the chain extender and bismaleimide (BM) crosslinker. By simply controlling the amount of BM, mechanical properties of the obtained crosslinked bio-PUs (CBPUs) were varied widely. In particular, the CBPU100 sample shows the highest tensile strength of 10.8 MPa, Young's modulus of 193 MPa, and an elongation of 155%. The differential scanning calorimetry experiments verify the recycle property of the CBPUs by the D-A/retro-D-A reaction at the proper temperature. The thermal recyclability and remolding ability of these materials are demonstrated by two kinds of polymer processing methods, i.e., solution casting and hot-compression molding. The recycled CBPUs display almost identical elongation and slightly decreased tensile strength compared to the as-synthesized samples. Furthermore, the CBPUs also exhibit excellent self-healing ability. Therefore, the resulting CBPUs possess tunable mechanical properties, good thermal recyclability, re-mending, and self-healing ability, which makes the bio-based materials more eco-friendly. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46272. |
学科主题 | Materials Science ; Physics ; Polymer Science |
语种 | 英语 |
公开日期 | 2018-12-04 |
内容类型 | 期刊论文 |
源URL | [http://ir.nimte.ac.cn/handle/174433/17424] |
专题 | 2018专题 |
推荐引用方式 GB/T 7714 | Wu, Qing-Yun,Gu, Lin. Recyclable bio-based crosslinked polyurethanes with self-healing ability[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2018,135(21). |
APA | Wu, Qing-Yun,&Gu, Lin.(2018).Recyclable bio-based crosslinked polyurethanes with self-healing ability.JOURNAL OF APPLIED POLYMER SCIENCE,135(21). |
MLA | Wu, Qing-Yun,et al."Recyclable bio-based crosslinked polyurethanes with self-healing ability".JOURNAL OF APPLIED POLYMER SCIENCE 135.21(2018). |
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