Performances of an Al-0.15 Bi-0.15 Pb-0.035 Ga alloy as an anode for Al-air batteries in neutral and alkaline electrolytes
Wang, Qin; Miao, He; Xue, Yejian; Sun, Shanshan; Li, Shihua; Liu, Zhaoping
刊名RSC ADVANCES
2017
卷号7期号:42页码:25838-25847
ISSN号2046-2069
英文摘要Aluminum is a very good candidate anode for metal-air batteries due to its negative electrode potential, high theoretical electrochemical equivalent value, abundant reserves and environmental friendliness. The corrosion behavior and electrochemical properties of the Al-1.5Bi-1.5Pb-0.035Ga alloy were investigated by self-corrosion tests and electrochemical techniques, and compared with that of pure Al and Al-Bi-Pb alloys. The performances of Al-air batteries based on these alloy anodes were studied by constant current discharge and I-V discharge tests. The corrosion morphology and discharge surface were also investigated by scanning electron microscopy (SEM)and energy dispersive X-ray (EDX) analysis. The results show that the Al-Bi-Pb-Ga alloy provides a more negative potential and exhibits an enhanced activity in NaCl solution compared with pure Al and Al-Bi-Pb alloys, and gives high power density (253.4 +/- 2.5 mW cm(-2)) and desirable anode efficiency (85.4 +/- 0.5%) when used as an anode for Al-air batteries in KOH solution. Moreover, the dissolution mechanism of the Al-Bi-Pb-Ga alloy is also characterized based on the electrochemical measurements and microstructure observations.
公开日期2017-12-25
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/14088]  
专题2017专题
推荐引用方式
GB/T 7714
Wang, Qin,Miao, He,Xue, Yejian,et al. Performances of an Al-0.15 Bi-0.15 Pb-0.035 Ga alloy as an anode for Al-air batteries in neutral and alkaline electrolytes[J]. RSC ADVANCES,2017,7(42):25838-25847.
APA Wang, Qin,Miao, He,Xue, Yejian,Sun, Shanshan,Li, Shihua,&Liu, Zhaoping.(2017).Performances of an Al-0.15 Bi-0.15 Pb-0.035 Ga alloy as an anode for Al-air batteries in neutral and alkaline electrolytes.RSC ADVANCES,7(42),25838-25847.
MLA Wang, Qin,et al."Performances of an Al-0.15 Bi-0.15 Pb-0.035 Ga alloy as an anode for Al-air batteries in neutral and alkaline electrolytes".RSC ADVANCES 7.42(2017):25838-25847.
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