A modified heteropoly acid catalyst with cetyltrimethylammonium bromide for methacrolein to methacrylic acid

doi:10.1016/j.jiec.2018.04.036

	A modified heteropoly acid catalyst with cetyltrimethylammonium bromide for methacrolein to methacrylic acid
	Cao, Yun-Li 1,2,3; Wang, Lei 1; Zhou, Li-Long 1,3; Xu, Bao-Hua 1; Diao, Yan-Yan 1; Zhang, Suo-Jiang 1
刊名	JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
	2018-09-25
卷号	65 页码:254-263
关键词	Heteropolyacids Cetyltrimethyl Ammonium Bromide Methacrolein Methacrylic Acid
ISSN号	1226-086X
DOI	10.1016/j.jiec.2018.04.036
英文摘要	A novel type of heteropolyacids, CTAB-CsH3PMo11VO40 (CTA-CsPAV), was developed by a method of emulsion synthesis using cetyltrimethyl ammonium bromide (CTAB) as the structure promoter, which was applied as a catalyst in the oxidation of methacrolein (MAL) to methacrylic acid (MM) with fixed-bed reactor. The structure and property of CTA-CsPAV were characterized by FT-IR, XRD, nitrogen adsorption-desorption, NH3-TPD, SEM, XPS, and so on. The structure-performance relationship of CTA-CsPAV was systematically studied, wherein the influence of surface area, acidity, redox property of CTA-CsPAV were focused and discussed. Importantly, the long-term performance of CTA-CsPAV was also investigated. (C) 2018 Published by Elsevier B.V. on behalf of The Korean Society of Industrial and Engineering Chemistry.
资助项目	Key Projects for Fundamental Research and Development of China[2016YFB0601303] ; International Cooperation and Exchange of the National Natural Science Foundation of China[51561145020] ; General Program of National Natural Science Foundation of China[21676277] ; Key Research Program of Frontier Sciences, CAS[QYZDY-SSW-JSC011] ; Fund of State Key Laboratory of Multiphase Complex Systems, IPE, CAS[MPCS-2015-A-05]
WOS关键词	Mixed Ammonium-cesium ; Selective Oxidation ; Esterification Reaction ; Clean Production ; Isobutyric Acid ; Isobutane ; Nmr ; Polysaccharides ; Fabrication ; Conversion
WOS研究方向	Chemistry ; Engineering
语种	英语
出版者	ELSEVIER SCIENCE INC
WOS记录号	WOS:000445990500029
资助机构	Key Projects for Fundamental Research and Development of China ; International Cooperation and Exchange of the National Natural Science Foundation of China ; General Program of National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; Fund of State Key Laboratory of Multiphase Complex Systems, IPE, CAS
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/26088]
专题	中国科学院过程工程研究所
通讯作者	Zhang, Suo-Jiang
作者单位	1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,CAS Key La, Beijing 100190, Peoples R China 2.Pingdingshan Univ, Pingdingshan 467000, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Cao, Yun-Li,Wang, Lei,Zhou, Li-Long,et al. A modified heteropoly acid catalyst with cetyltrimethylammonium bromide for methacrolein to methacrylic acid[J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,2018,65:254-263.
APA	Cao, Yun-Li,Wang, Lei,Zhou, Li-Long,Xu, Bao-Hua,Diao, Yan-Yan,&Zhang, Suo-Jiang.(2018).A modified heteropoly acid catalyst with cetyltrimethylammonium bromide for methacrolein to methacrylic acid.JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,65,254-263.
MLA	Cao, Yun-Li,et al."A modified heteropoly acid catalyst with cetyltrimethylammonium bromide for methacrolein to methacrylic acid".JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY 65(2018):254-263.