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Low temperature selective catalytic reduction of NOX with NH3 by activated coke loaded with FexCoyCezOm: The enhanced activity, mechanism and kinetics
Lu, Pei1,2; Li, Rui1,2; Xing, Yi1,2; Li, Yuran3; Zhu, Tingyu3; Yue, Huifang1,2; Wu, Wanrong1,2
刊名FUEL
2018-12-01
卷号233页码:188-199
关键词Activated Coke Low-temperature Scr Nox The Enhanced Activity Mechanism And Kinetics
ISSN号0016-2361
DOI10.1016/j.fuel.2018.05.076
英文摘要

The existing catalysts based on activated coke had generally poor denitration performance at low temperature, which could not meet the urgent needs of power plants and steel enterprises. In this study, activated coke loaded with FexCoyCezOm was prepared by incipient wetness impregnation method and employed to remove NOx at 100-350 degrees C in simulated flue gas. 3% Fe0.6Co0.2Ce0.2O1.57/AC catalyst exhibited highest NOx removal efficiency as it had more than 70% NOx conversion rate at 100 degrees C and achieved more than 90% denitrition efficiency at 250-350 degrees C. The catalyst also showed stable catalytic performance and good resistance to H2O or/and SO2 at 250 degrees C. Based on the results of Brunauer-Emmett-Teller (BET), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), temperature programmed desorption (TPD), temperature programmed reduction (TPR) and Fourier transform infrared spectroscopy (FTIR), the enhanced performance could be attributed to the co-participation of Fe, Co and Ce species with different valence states, the high concentration of chemisorbed oxygen, highly dispersed active components, the increase of weak acid sites, good redox properties of metallic oxides and abundant founctional groups on the catalyts surface. Finally, the possible mechanism and kinetics of NOx removal over FexCoyCezOm/AC catalyst were discussed in detail, which revealed that the enhanced performance was resulted from the increased active sites and the redox cycle among Fe, Co and Ce.

资助项目National Key R&D Program of China[2017YFC0210303] ; Beijing Science and Technology Project[D161100004516001] ; Open fund of National Engineering Laboratory for Mobile Source Emission Control Technology[NELMS2017A14] ; Fundamental Research Funds for the Central Universities
WOS关键词Simulated Flue-gas ; Dispersed Mnox/sapo-34 Catalyst ; Elemental Mercury ; Simultaneous Removal ; Sulfur Resistance ; Nitrogen-oxides ; So2 Resistance ; Performance ; Nh3-scr ; Scr
WOS研究方向Energy & Fuels ; Engineering
语种英语
出版者ELSEVIER SCI LTD
WOS记录号WOS:000441893200020
资助机构National Key R&D Program of China ; Beijing Science and Technology Project ; Open fund of National Engineering Laboratory for Mobile Source Emission Control Technology ; Fundamental Research Funds for the Central Universities
内容类型期刊论文
源URL[http://ir.ipe.ac.cn/handle/122111/25938]  
专题中国科学院过程工程研究所
通讯作者Xing, Yi
作者单位1.Univ Sci & Technol Beijing, Sch Energy & Environm Engn, Beijing 100083, Peoples R China
2.Univ Sci & Technol Beijing, Beijing Key Lab Resource Oriented Treatment Ind P, Beijing 100083, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Cleaner Hydromet Prod Technol, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Lu, Pei,Li, Rui,Xing, Yi,et al. Low temperature selective catalytic reduction of NOX with NH3 by activated coke loaded with FexCoyCezOm: The enhanced activity, mechanism and kinetics[J]. FUEL,2018,233:188-199.
APA Lu, Pei.,Li, Rui.,Xing, Yi.,Li, Yuran.,Zhu, Tingyu.,...&Wu, Wanrong.(2018).Low temperature selective catalytic reduction of NOX with NH3 by activated coke loaded with FexCoyCezOm: The enhanced activity, mechanism and kinetics.FUEL,233,188-199.
MLA Lu, Pei,et al."Low temperature selective catalytic reduction of NOX with NH3 by activated coke loaded with FexCoyCezOm: The enhanced activity, mechanism and kinetics".FUEL 233(2018):188-199.
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