Nanoscale Observation of Microfibril Swelling and Dissolution in Ionic Liquids | |
Xu, Junli1; Zhang, Baocai2; Lu, Xingmei1,3; Zhou, Yihua2; Fang, Jinyun4; Li, Yao1; Zhang, Suojiang1,3 | |
刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING |
2018 | |
卷号 | 6期号:1页码:909-917 |
关键词 | Ionic Liquids Biomass Swelling Cellulose Microfibrils |
ISSN号 | 2168-0485 |
DOI | 10.1021/acssuschemeng.7b03269 |
文献子类 | Article |
英文摘要 | Ionic liquids (ILs) are widely used for biomass pretreatment because of their excellent dissolving capacity. The efficient and economical use of ILs in pretreatment greatly depends on revealing the underlying mechanism of biomass dissolution. Here, we observed that cellulose microfibrils of rice straw swelled in ILs using atomic force microscopy, and the swelling resulted in a decrease in cellulose crystallinity as determined by time-course X-ray diffraction analysis. The swelling of the IL-induced cellulose microfibrils greatly promoted the saccharification efficiency of rice straw. Compared with conventional acid or alkali solutions, strong hydrogen bond interactions between ILs of the appropriate size and polysaccharides resulted in cellulose microfibrils swelling in ILs, which was demonstrated by nuclear magnetic resonance and molecular simulation. Therefore, microfibril swelling is the key step in cellulose dissolution with ILs; effective swelling could accelerate cellulose dissolution and biomass pretreatment. Thus, those results are helpful in understanding the mechanism of lignocellulose dissolution in ILs and developing new ILs for biomass pretreatment. |
WOS关键词 | Biomass Recalcitrance ; Enzymatic Digestibility ; Lignocellulosic Biomass ; Molecular Simulation ; Cellulose Fiber ; Hydrogen-bonds ; Corn Stover ; Force-field ; Pretreatment ; Hydrolysis |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
语种 | 英语 |
WOS记录号 | WOS:000419536800096 |
资助机构 | National Natural Science Foundation of China(21606240 ; 21210006 ; 21336002 ; 21476234) |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/24085] |
专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,Key Lab Gr, 1 North 2nd St, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Genet & Dev Biol, State Key Lab Plant Genom, 1 West Beichen Rd, Beijing 100101, Peoples R China 3.Univ Chinese Acad Sci, Sch Chem & Chem Engn, 19A Yuquan Rd, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Tech Inst Phys & Chem, 29 Zhongguancun East Rd, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Junli,Zhang, Baocai,Lu, Xingmei,et al. Nanoscale Observation of Microfibril Swelling and Dissolution in Ionic Liquids[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(1):909-917. |
APA | Xu, Junli.,Zhang, Baocai.,Lu, Xingmei.,Zhou, Yihua.,Fang, Jinyun.,...&Zhang, Suojiang.(2018).Nanoscale Observation of Microfibril Swelling and Dissolution in Ionic Liquids.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(1),909-917. |
MLA | Xu, Junli,et al."Nanoscale Observation of Microfibril Swelling and Dissolution in Ionic Liquids".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.1(2018):909-917. |
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