Quantitative and structural analysis of minerals in soil clay fractions developed under different climate zones in China by XRD with Rietveld method, and its implications for pedogenesis

doi:10.1016/j.clay.2018.05.019

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	Quantitative and structural analysis of minerals in soil clay fractions developed under different climate zones in China by XRD with Rietveld method, and its implications for pedogenesis
	Tan, WF (reprint author), Chinese Acad Sci, State Key Lab Soil Eros & Dryland Fanning Loess P, Inst Soil & Water Conservat, Yangling 712100, Shaanxi, Peoples R China.; Wei Zhao 2,3; Wen-Feng Tan 1,3; Tan, WF (reprint author), Minist Water Resources, Yangling 712100, Shaanxi, Peoples R China.
刊名	APPLIED CLAY SCIENCE
	2018
卷号	162 页码:351-361
关键词	X-ray Diffraction Quantification Clay Minerals Iron (Hydr)Oxides Soil Development
ISSN号	0169-1317
DOI	10.1016/j.clay.2018.05.019
文献子类	Article
英文摘要	Mineral compositions and structures in soil clay fractions can reflect the pedogenesis and the pedoenvironments of the natural soils. However, the simultaneous quantification and structural analysis of all phases in soils by X-ray diffraction are difficult, mainly due to overlapping reflections. In this study, quantification and structural analysis of the mineral phases in clay fractions in five soils (Alliti-Udic Ferrosol, Claypani-Udic Argosol, and Hapli-Udic Argosol, Malan loess, and Paleosol), developed under different climate zones in China, were carried out by the Rietveld method. Before proceeding with these analyses for the natural soil clay fractions by the Rietveld method, this method was applied to a set of artificial soils of montmorillonite (including a 6.8% quartz impurity), kaolinite, goethite, hematite, and magnetite to evaluate the accuracy of the method. Moreover, in the Rietveld method, the structure phase models, background function, profile models, the initial values for the correction of preferred orientation, and sequence of operations in Rietveld refinement parameters were optimized to improve the accuracy of the method. The evaluation demonstrated the quantitative analysis by the Rietveld method can obtain relatively satisfied results. The absolute errors for the mineral contents below 5% were in the range of - 0.49%- + 0.63%, and those for the mineral contents above 10% were in the range of - 6.32%-+ 5.00%. The absolute errors for the Al-substitutions in the goethite and hematite are - 0.8 Al mol %-+ 3.2 Al mol% and - 0.3 Al mol%-+ 3.3 Al mol%, respectively. Employing the above Rietveld method, the content of every mineral and Al-substituted iron (hydr)oxides (goethite and hematite) in the clay fractions in the five soils developed under different climate zones were obtained. In combined with the soil physicochemical properties, the order of pedogenic development of the five natural soils is Alliti-Udic Ferrosol > Claypani-Udic Argosol > Hapli-Udic Argosol and > Malan loess, respectively.
学科主题	Chemistry ; Materials Science ; Mineralogy
出版地	PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000440775900038
资助机构	National Natural Science Foundation of China [41101218, 41330852] ; National Natural Science Foundation of China [41101218, 41330852] ; Northwest AF University [Z109021120] ; Northwest AF University [Z109021120] ; Western Light Project of the Chinese Academy of Sciences [K318001103] ; Western Light Project of the Chinese Academy of Sciences [K318001103] ; National Natural Science Foundation of China [41101218, 41330852] ; National Natural Science Foundation of China [41101218, 41330852] ; Northwest AF University [Z109021120] ; Northwest AF University [Z109021120] ; Western Light Project of the Chinese Academy of Sciences [K318001103] ; Western Light Project of the Chinese Academy of Sciences [K318001103]
内容类型	期刊论文
源URL	[http://ir.iswc.ac.cn/handle/361005/8185]
专题	水保所科研产出--SCI_2018--SCI
通讯作者	Tan, WF (reprint author), Chinese Acad Sci, State Key Lab Soil Eros & Dryland Fanning Loess P, Inst Soil & Water Conservat, Yangling 712100, Shaanxi, Peoples R China.; Tan, WF (reprint author), Minist Water Resources, Yangling 712100, Shaanxi, Peoples R China.
作者单位	1.Minist Water Resources, Yangling 712100, Shaanxi, Peoples R China 2.Northwest A&F Univ, State Key Lab Soil Eros & Dryland Fanning Loess P, Yangling 712100, Shaanxi, Peoples R China 3.Chinese Acad Sci, State Key Lab Soil Eros & Dryland Fanning Loess P, Inst Soil & Water Conservat, Yangling 712100, Shaanxi, Peoples R China 4.Huazhong Agr Univ, Coll Resources & Environm, Wuhan 430070, Hubei, Peoples R China
推荐引用方式 GB/T 7714	Tan, WF ,Wei Zhao,Wen-Feng Tan,et al. Quantitative and structural analysis of minerals in soil clay fractions developed under different climate zones in China by XRD with Rietveld method, and its implications for pedogenesis[J]. APPLIED CLAY SCIENCE,2018,162:351-361.
APA	Tan, WF ,Wei Zhao,Wen-Feng Tan,&Tan, WF .(2018).Quantitative and structural analysis of minerals in soil clay fractions developed under different climate zones in China by XRD with Rietveld method, and its implications for pedogenesis.APPLIED CLAY SCIENCE,162,351-361.
MLA	Tan, WF ,et al."Quantitative and structural analysis of minerals in soil clay fractions developed under different climate zones in China by XRD with Rietveld method, and its implications for pedogenesis".APPLIED CLAY SCIENCE 162(2018):351-361.