Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots

doi:10.1002/cssc.201701127

CORC > 青岛生物能源与过程研究所 > 中国科学院青岛生物能源与过程研究所 > 低碳催化转化团队

	Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots
	Ji, Guijie 1; Duan, Yanan 1; Zhang, Shaochun 1; Fei, Benhua 2; Chen, Xiufang 1; Yang, Yong 1
刊名	CHEMSUSCHEM
	2017-09-11
卷号	10 期号:17 页码:3427-3434
关键词	Alkyne Hydrogenation Carbon Materials Nanoparticles Semihydrogenation Palladium
DOI	10.1002/cssc.201701127
文献子类	Article
英文摘要	Highly dispersed palladium nanoparticles (Pd NPs) immobilized on heteroatom-doped hierarchical porous carbon supports (N,O-carbon) with large specific surface areas are synthesized by a wet chemical reduction method. The N,O-carbon derived from naturally abundant bamboo shoots is fabricated by a tandem hydrothermal-carbonization process without assistance of any templates, chemical activation reagents, or exogenous N or O sources in a simple and ecofriendly manner. The prepared Pd/N,O-carbon catalyst shows extremely high activity and excellent chemoselectivity for semihydrogenation of a broad range of alkynes to versatile and valuable alkenes under ambient conditions. The catalyst can be readily recovered for successive reuse with negligible loss in activity and selectivity, and is also applicable for practical gram-scale reactions.
WOS关键词	NANOPOROUS GOLD CATALYST ; STEREOSELECTIVE SEMIHYDROGENATION ; CIS-ALKENES ; HYDROGENATION REACTIONS ; PALLADIUM ; EFFICIENT ; REDUCTION ; DESIGN ; WATER ; SUPERCAPACITORS
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000410136800016
资助机构	Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences(Y6710619KL) ; 13th Five-Year National key R D projects(2017YFD0600805)
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/9739]
专题	青岛生物能源与过程研究所_低碳催化转化团队
作者单位	1.Chinese Acad Sci, CAS Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Int Ctr Bamboo & Rattan, Beijing 100102, Peoples R China
推荐引用方式 GB/T 7714	Ji, Guijie,Duan, Yanan,Zhang, Shaochun,et al. Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots[J]. CHEMSUSCHEM,2017,10(17):3427-3434.
APA	Ji, Guijie,Duan, Yanan,Zhang, Shaochun,Fei, Benhua,Chen, Xiufang,&Yang, Yong.(2017).Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots.CHEMSUSCHEM,10(17),3427-3434.
MLA	Ji, Guijie,et al."Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots".CHEMSUSCHEM 10.17(2017):3427-3434.