Research Progress on Polycarbonate-based Solid-state Polymer Electrolytes | |
Dong, Tian-tian1; Zhang, Jian-jun2; Chai, Jing-chao2; Jia, Qing-ming1; Cui, Guang-lei2 | |
刊名 | ACTA POLYMERICA SINICA
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2017-06-20 | |
期号 | 6页码:906-921 |
关键词 | Polycarbonate Solid-state Polymer Electrolyte Lithium Battery Classification And Performance Ionic Transportation Mechanism |
DOI | 10.11777/j.issn1000-3304.2017.16333 |
文献子类 | Review |
英文摘要 | Rechargeable lithium ion batteries become an very important technology in the contemporary society. They are expanding their application in electric vehicles and power grids. However, current lithium ion batteries with liquid electrolyte have been suffering from potential safety crisis mainly due to their highly flammable organic liquid carbonate organic electrolyte and explosion hazards. These potential risks (combustion and explosion) would retard the commercialization of electric vehicles or hybrid electric vehicles. Thus, the safety issue of lithium ion battery merits further study. Solid electrolytes have attracted ever-increasing interest owing to their enhanced safety issue and higher energy density of lithium battery. Solid electrolyte materials mainly include inorganic solid electrolytes (ISEs) and solid polymer electrolytes (SPEs). The ISEs are classified into oxide-based, sulfide-based and etc. However, in spite of the presence of highly ion conductive ISEs, there are still many undergoing issues that limit the practical application at the present stage, like the large interface impedance between electrode and ISEs and the difficulty of processing. More attention has been paid to solid polymer electrolytes due to their superior flexibility and processability, which are also subjected to thermal expansion at elevated temperature. Poly(ethylene oxide) (PEO) solid polymer electrolyte has undergone a sort of renaissance in the past few decades. However, the quintessential frailty of PEO solid polymer electrolyte is low ionic conductivity (in the order of 10(-7) S cm(-1)) at room temperature with a relatively narrow electrochemical window. Hence, it is essential to develop new solid polymer electrolytes with comprehensive performance in terms of high ionic conductivity, wide electrochemical window, superior mechanical strength, excellent thermal stability as well as good interfacial compatibility. In this review, a series of polycarbonate-based solid polymer electrolytes (such as PEC, PPC, PTMC and PVC et al.) are summarized. In addition, we also present a brief review on preparation, electrochemical property, modification, ionic transportation mechanism and future development direction for each of these solid polymer electrolytes. |
WOS关键词 | CO-ETHYLENE CARBONATE) ; LITHIUM-ION BATTERIES ; POLY(TRIMETHYLENE CARBONATE) ; EPSILON-CAPROLACTONE ; GEL ELECTROLYTE ; COPOLYMERS ; NANOPARTICLES ; CONDUCTION ; BEHAVIOR ; LIQUID |
WOS研究方向 | Polymer Science |
语种 | 英语 |
WOS记录号 | WOS:000405191000003 |
内容类型 | 期刊论文 |
源URL | [http://ir.qibebt.ac.cn/handle/337004/9634] ![]() |
专题 | 青岛生物能源与过程研究所_仿生能源与储能系统团队 |
作者单位 | 1.Kunming Univ Sci & Technol, Fac Chem Engn, Kunming 650500, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Ind Energy Storage Technol Inst, Qingdao 266101, Peoples R China |
推荐引用方式 GB/T 7714 | Dong, Tian-tian,Zhang, Jian-jun,Chai, Jing-chao,et al. Research Progress on Polycarbonate-based Solid-state Polymer Electrolytes[J]. ACTA POLYMERICA SINICA,2017(6):906-921. |
APA | Dong, Tian-tian,Zhang, Jian-jun,Chai, Jing-chao,Jia, Qing-ming,&Cui, Guang-lei.(2017).Research Progress on Polycarbonate-based Solid-state Polymer Electrolytes.ACTA POLYMERICA SINICA(6),906-921. |
MLA | Dong, Tian-tian,et al."Research Progress on Polycarbonate-based Solid-state Polymer Electrolytes".ACTA POLYMERICA SINICA .6(2017):906-921. |
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