Highly Efficient Indirect Hydration of Olefins to Alcohols Using Superacidic Polyoxometalate-Based Ionic Hybrids Catalysts

doi:10.1021/acs.lecr.8b00535

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 磁共振应用研究部

	Highly Efficient Indirect Hydration of Olefins to Alcohols Using Superacidic Polyoxometalate-Based Ionic Hybrids Catalysts
	Tao, Duan-Jian 3; Cao, Zhi-Jun 3; Zhao, Xin 3; He, Fei-Qjang 3; Zhou, Yan 3; Huang, Kuan 1; Zheng, An-Min 2
刊名	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
	2018-05-16
卷号	57 期号:19 页码:6654-6663
DOI	10.1021/acs.lecr.8b00535
文献子类	Article
英文摘要	Improving the catalytic efficiency in the hydration of olefins to alcohols is an important yet challenging issue in acid catalysis. Herein, a series of novel superacidic polyoxometalate-based ionic hybrids were prepared and employed as catalysts for highly efficient indirect hydration of olefins to corresponding alcohols. Several characterization techniques such as FT-IR spectra, XRD, SEM, and P-31 MAS NMR spectroscopy were performed to characterize the structures of these superacid hybrids and their acid properties. The results show that the catalytic performances of ionic hybrids were closely related to their acidic strength. The superacidic ionic hybrid [BPy-SO3H-OTf]PW was found to be the best active catalyst to obtain the corresponding alcohols with good yields. The catalytic efficiency in indirect hydration process using superacidic ionic hybrid catalysts is obviously superior to that of direct hydration, which thus opens up a new way to improve the efficiency of the current hydration process.
WOS关键词	REACTIVE-DISTILLATION PROCESS ; SOLID ACID CATALYSTS ; SELECTIVE OXIDATION ; ROOM-TEMPERATURE ; LIQUID CATALYST ; CYCLOHEXANOL ; ESTERIFICATION ; TRANSESTERIFICATION ; DEPOLYMERIZATION ; CYCLOPENTANOL
WOS研究方向	Engineering
语种	英语
WOS记录号	WOS:000432752800008
资助机构	National Natural Science Foundations of China(21566011 ; National Natural Science Foundations of China(21566011 ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars(20162BCB23026) ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars(20162BCB23026) ; Science & Technology Programs of Jiangxi Province Department of Education(GJJ160272) ; Science & Technology Programs of Jiangxi Province Department of Education(GJJ160272) ; 31570560) ; 31570560) ; National Natural Science Foundations of China(21566011 ; National Natural Science Foundations of China(21566011 ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars(20162BCB23026) ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars(20162BCB23026) ; Science & Technology Programs of Jiangxi Province Department of Education(GJJ160272) ; Science & Technology Programs of Jiangxi Province Department of Education(GJJ160272) ; 31570560) ; 31570560)
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/11981]
专题	武汉物理与数学研究所_磁共振应用研究部
作者单位	1.Nanchang Univ, Sch Resources Environm & Chem Engn, Minist Educ, Key Lab Poyang Lake Environm & Resource Utilizat, Nanchang 330031, Jiangxi, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan 430071, Hubei, Peoples R China 3.Jiangxi Normal Univ, Coll Chem & Chem Engn, Inst Adv Mat, Nanchang 330022, Jiangxi, Peoples R China
推荐引用方式 GB/T 7714	Tao, Duan-Jian,Cao, Zhi-Jun,Zhao, Xin,et al. Highly Efficient Indirect Hydration of Olefins to Alcohols Using Superacidic Polyoxometalate-Based Ionic Hybrids Catalysts[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2018,57(19):6654-6663.
APA	Tao, Duan-Jian.,Cao, Zhi-Jun.,Zhao, Xin.,He, Fei-Qjang.,Zhou, Yan.,...&Zheng, An-Min.(2018).Highly Efficient Indirect Hydration of Olefins to Alcohols Using Superacidic Polyoxometalate-Based Ionic Hybrids Catalysts.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,57(19),6654-6663.
MLA	Tao, Duan-Jian,et al."Highly Efficient Indirect Hydration of Olefins to Alcohols Using Superacidic Polyoxometalate-Based Ionic Hybrids Catalysts".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 57.19(2018):6654-6663.