Zirconium Oxide Supported Palladium Nanoparticles as a Highly Efficient Catalyst in the Hydrogenation-Amination of Levulinic Acid to Pyrrolidones

doi:10.1002/cctc.201600739

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 磁共振应用研究部

	Zirconium Oxide Supported Palladium Nanoparticles as a Highly Efficient Catalyst in the Hydrogenation-Amination of Levulinic Acid to Pyrrolidones
	Wang, Guoxiong 2,3; Wang, Chengtao 2,3; Yi, Xianfeng 4; Wang, Liang 2,3; Zhang, Jian 2,3; Xie, Bin 2,3,5; Xiao, Feng-Shou 1,2,3; Zheng, Anmin 4; Dai, Zhifeng 2,3
刊名	CHEMCATCHEM
	2017-07-24
卷号	9 期号:14 页码:2661-2667
关键词	Biomass Hydrogenation Palladium Supported Catalysts Zirconium
DOI	10.1002/cctc.201600739
文献子类	Article
英文摘要	The selective hydrogenation-amination of levulinic acid into pyrrolidones is regarded as one of the most important reactions to transform biomass-derived lignocellulose feedstocks into valuable chemicals. Here we report on ZrO2-supported Pd nanoparticles as a highly active, chemoselective, and reusable catalyst for the hydrogenation-amination of levulinic acid with H-2 and various amines under mild reaction conditions. The Pd/ZrO2 catalyst exhibited a marked increase in activity compared with conventional Pd catalysts and a significant enhancement in pyrrolidone selectivity. The excellent catalytic performances are reasonably attributed to the ZrO2 support, which has strong Lewis acidity to enhance the hydrogenation-amination reaction and hinder side reactions.
WOS关键词	GAMMA-VALEROLACTONE ; PD NANOPARTICLES ; SELECTIVE HYDROGENATION ; HETEROGENEOUS CATALYSTS ; FORMIC-ACID ; SOLID ACID ; CARBOHYDRATE BIOMASS ; REDUCTIVE AMINATION ; PHASE HYDROGENATION ; CARBON NANOTUBES
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000406243100009
资助机构	National Natural Science Foundation of China(21333009 ; National Natural Science Foundation of China(21333009 ; U1462202 ; U1462202 ; 21403192 ; 21403192 ; 21522310) ; 21522310) ; National Natural Science Foundation of China(21333009 ; National Natural Science Foundation of China(21333009 ; U1462202 ; U1462202 ; 21403192 ; 21403192 ; 21522310) ; 21522310)
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/11442]
专题	武汉物理与数学研究所_磁共振应用研究部
作者单位	1.Zhejiang Univ, Key Lab Biomass Chem Engn, Minist Educ, Hangzhou 310027, Zhejiang, Peoples R China 2.Zhejiang Univ, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Zhejiang, Peoples R China 3.Zhejiang Univ, Dept Chem, Hangzhou 310028, Zhejiang, Peoples R China 4.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Hubei, Peoples R China 5.Petrochina Petrochem Res Inst, Beijing 102206, Peoples R China
推荐引用方式 GB/T 7714	Wang, Guoxiong,Wang, Chengtao,Yi, Xianfeng,et al. Zirconium Oxide Supported Palladium Nanoparticles as a Highly Efficient Catalyst in the Hydrogenation-Amination of Levulinic Acid to Pyrrolidones[J]. CHEMCATCHEM,2017,9(14):2661-2667.
APA	Wang, Guoxiong.,Wang, Chengtao.,Yi, Xianfeng.,Wang, Liang.,Zhang, Jian.,...&Dai, Zhifeng.(2017).Zirconium Oxide Supported Palladium Nanoparticles as a Highly Efficient Catalyst in the Hydrogenation-Amination of Levulinic Acid to Pyrrolidones.CHEMCATCHEM,9(14),2661-2667.
MLA	Wang, Guoxiong,et al."Zirconium Oxide Supported Palladium Nanoparticles as a Highly Efficient Catalyst in the Hydrogenation-Amination of Levulinic Acid to Pyrrolidones".CHEMCATCHEM 9.14(2017):2661-2667.