Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology

doi:10.1007/s40242-017-7050-9

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 磁共振应用研究部

	Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology
	Xu Ruren 2; Wang Chao 1; Xu Jun 1; Wang Aitian 2; Yan Wenfu 2; Deng Feng 1
刊名	CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
	2017-08-01
卷号	33 期号:4 页码:513-519
关键词	Zeolite Aluminophosphate Templating Effect Structure-directing Effect
DOI	10.1007/s40242-017-7050-9
文献子类	Article
英文摘要	Three layered aluminophosphates(UiO-15, APDAP(12)-150 and APDAP-150) with same topology were crystallized from an initial mixture with a molar composition of AL(2)O(3):1.5P(2)O(5):5.5R:227H(2)O, where R is ethylenediamine, 1,2-diaminopropane or 1,3-diaminopropane, respectively. The crystallization processes of UiO-15, APDAP(12)-150 and APDAP-150 were investigated using solid-state NMR in combination with XRD and other characterization techniques. The evolution of the coordination states of Al and P in the solid products was monitored, and the possible starting points of crystallization(core units) of UiO-15, APDAP(12)-150 and APDAP-150 were obtained and analyzed. The formation of a trimer as well as a hexamer of aluminophosphate, a monomer of PO4 and a nonamer containing two three-membered rings is critical for the start of crystallization of UiO-15. The formation of a hexamer and a pentamer is critical for the start of crystallization of APDAP(12)-150. The formation of an AlO6 monomer and a pentamer containing a three-membered ring is critical for the start of crystallization of APDAP-150. The crystal water played a co-structure-directing role in the formation of APDAP-150.
WOS关键词	OPEN-FRAMEWORK ALUMINOPHOSPHATES ; ORGANIC-MOLECULES ; ZEOLITE SYNTHESIS ; MICROPOROUS ALUMINOPHOSPHATES ; GUEST/HOST RELATIONSHIPS ; TEMPERATURE-DEPENDENCE ; CRYSTAL-STRUCTURE ; INITIAL-STAGE ; CRYSTALLIZATION ; PIPERAZINE
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000407988500001
资助机构	National Natural Science Foundation of China(21571075 ; National Natural Science Foundation of China(21571075 ; National Key Research and Development Program of China(2016YFB0701100) ; National Key Research and Development Program of China(2016YFB0701100) ; 21320102001 ; 21320102001 ; 21621001) ; 21621001) ; National Natural Science Foundation of China(21571075 ; National Natural Science Foundation of China(21571075 ; National Key Research and Development Program of China(2016YFB0701100) ; National Key Research and Development Program of China(2016YFB0701100) ; 21320102001 ; 21320102001 ; 21621001) ; 21621001)
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/11349]
专题	武汉物理与数学研究所_磁共振应用研究部
作者单位	1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 2.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China
推荐引用方式 GB/T 7714	Xu Ruren,Wang Chao,Xu Jun,et al. Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2017,33(4):513-519.
APA	Xu Ruren,Wang Chao,Xu Jun,Wang Aitian,Yan Wenfu,&Deng Feng.(2017).Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,33(4),513-519.
MLA	Xu Ruren,et al."Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 33.4(2017):513-519.