Synthesis of 2-AryI-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines | |
Asiri, Abdullah M.2; Alamry, Khalid A.2; Liu, Chao-Yang1; Liu, Li3,4; Huang, Yong-Shun3,4; Zhong, Xin-Xin3,4; Li, Fa-Bao3,4; Wang, Hui-Juan1; Zhang, Meng3,4 | |
刊名 | JOURNAL OF ORGANIC CHEMISTRY |
2017-08-18 | |
卷号 | 82期号:16页码:8617-8627 |
DOI | 10.1021/acs.joc.7b01507 |
文献子类 | Article |
英文摘要 | The metal-free-mediated thermal reaction of [60]fullerene with aromatic aldehydes and inactive primary amines bearing electron-donating groups at the alpha-position afforded a series of 2-aryl-5-alkyl-fulleropyrtolidines, including the scarce 27 aryl-5-benzyl-fulleropyrrolidines as a mixture of cis and trans isomers. With rare exceptions, the mixture of, cis, and trans isomers could be easily isolated by column chromatography, with a preference of cis isomers as Major products. A plausible mechanism for the formation of fulleropyrrolidines is also proposed. |
WOS关键词 | ONE-STEP REACTION ; FERRIC PERCHLORATE ; 1,3-DIPOLAR CYCLOADDITION ; FULLERENE DERIVATIVES ; AZOMETHINE YLIDES ; FACILE ACCESS ; ACID ESTERS ; FULLEROPYRROLIDINES ; C-60 ; FUNCTIONALIZATION |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000408285500028 |
资助机构 | National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; Scientific Research Foundation of Education Commission of Hubei Province(D20161007) ; Scientific Research Foundation of Education Commission of Hubei Province(D20161007) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; 21671061) ; 21671061) ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; Scientific Research Foundation of Education Commission of Hubei Province(D20161007) ; Scientific Research Foundation of Education Commission of Hubei Province(D20161007) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; 21671061) ; 21671061) |
内容类型 | 期刊论文 |
源URL | [http://ir.wipm.ac.cn/handle/112942/11340] |
专题 | 武汉物理与数学研究所_高技术创新与发展中心 |
作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 2.King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 21589, Saudi Arabia 3.Hubei Univ, Sch Chem & Chem Engn, Wuhan 430062, Hubei, Peoples R China 4.Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Hubei, Peoples R China |
推荐引用方式 GB/T 7714 | Asiri, Abdullah M.,Alamry, Khalid A.,Liu, Chao-Yang,et al. Synthesis of 2-AryI-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines[J]. JOURNAL OF ORGANIC CHEMISTRY,2017,82(16):8617-8627. |
APA | Asiri, Abdullah M..,Alamry, Khalid A..,Liu, Chao-Yang.,Liu, Li.,Huang, Yong-Shun.,...&Zhang, Meng.(2017).Synthesis of 2-AryI-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines.JOURNAL OF ORGANIC CHEMISTRY,82(16),8617-8627. |
MLA | Asiri, Abdullah M.,et al."Synthesis of 2-AryI-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines".JOURNAL OF ORGANIC CHEMISTRY 82.16(2017):8617-8627. |
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