Synthesis of 2-AryI-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines | |
Liu, Chao-Yang3; Asiri, Abdullah M.4; Wang, Hui-Juan3; Li, Fa-Bao1,2; Zhong, Xin-Xin1,2; Zhang, Meng1,2; Huang, Yong-Shun1,2; Liu, Li1,2; Alamry, Khalid A.4 | |
刊名 | JOURNAL OF ORGANIC CHEMISTRY |
2017-08-18 | |
卷号 | 82期号:16页码:8617-8627 |
DOI | 10.1021/acs.joc.7b01507 |
文献子类 | Article |
英文摘要 | The metal-free-mediated thermal reaction of [60]fullerene with aromatic aldehydes and inactive primary amines bearing electron-donating groups at the alpha-position afforded a series of 2-aryl-5-alkyl-fulleropyrtolidines, including the scarce 27 aryl-5-benzyl-fulleropyrrolidines as a mixture of cis and trans isomers. With rare exceptions, the mixture of, cis, and trans isomers could be easily isolated by column chromatography, with a preference of cis isomers as Major products. A plausible mechanism for the formation of fulleropyrrolidines is also proposed. |
WOS关键词 | ONE-STEP REACTION ; FERRIC PERCHLORATE ; 1,3-DIPOLAR CYCLOADDITION ; FULLERENE DERIVATIVES ; AZOMETHINE YLIDES ; FACILE ACCESS ; ACID ESTERS ; FULLEROPYRROLIDINES ; C-60 ; FUNCTIONALIZATION |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000408285500028 |
资助机构 | National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; Scientific Research Foundation of Education Commission of Hubei Province(D20161007) ; Scientific Research Foundation of Education Commission of Hubei Province(D20161007) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; 21671061) ; 21671061) ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; Scientific Research Foundation of Education Commission of Hubei Province(D20161007) ; Scientific Research Foundation of Education Commission of Hubei Province(D20161007) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; 21671061) ; 21671061) |
内容类型 | 期刊论文 |
源URL | [http://ir.wipm.ac.cn/handle/112942/11330] |
专题 | 武汉物理与数学研究所_高技术创新与发展中心 |
作者单位 | 1.Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Hubei, Peoples R China 2.Hubei Univ, Sch Chem & Chem Engn, Wuhan 430062, Hubei, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 4.King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 21589, Saudi Arabia |
推荐引用方式 GB/T 7714 | Liu, Chao-Yang,Asiri, Abdullah M.,Wang, Hui-Juan,et al. Synthesis of 2-AryI-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines[J]. JOURNAL OF ORGANIC CHEMISTRY,2017,82(16):8617-8627. |
APA | Liu, Chao-Yang.,Asiri, Abdullah M..,Wang, Hui-Juan.,Li, Fa-Bao.,Zhong, Xin-Xin.,...&Alamry, Khalid A..(2017).Synthesis of 2-AryI-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines.JOURNAL OF ORGANIC CHEMISTRY,82(16),8617-8627. |
MLA | Liu, Chao-Yang,et al."Synthesis of 2-AryI-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines".JOURNAL OF ORGANIC CHEMISTRY 82.16(2017):8617-8627. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论