Transition-metal-free PhI(OAc)(2)-promoted highly selective hydroboration of terminal alkynes under air

doi:10.1039/c7ra03680a

	Transition-metal-free PhI(OAc)(2)-promoted highly selective hydroboration of terminal alkynes under air
	Zhang, Q; Wei, W (reprint author), Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China.; Zhang, Q (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China.; Wei, W; Ji, JX; Liang, W; Zhang, ZJ; Fu, Q; Yi, D; Yang, L
刊名	RSC ADVANCES
	2017
卷号	7 期号:42 页码:26070-26073
DOI	10.1039/c7ra03680a
产权排序	1
文献子类	Article
英文摘要	A new transition-metal-free PhI(OAc)(2)-promoted hydroboration reaction of terminal alkynes with bis(pinacolato) diboron has been developed at room temperature under air. A series of vinyl boronates could be conveniently and efficiently obtained in moderate to good yields with good regioselectivity and stereoselectivity as well as favorable functional group tolerance. The key I-B intermediates were first demonstrated in the present reaction system that explains the proposed mechanism.
学科主题	Chemistry
语种	英语
资助机构	We gratefully acknowledge financial support from the Chinese National Natural Science Foundation (No. 21402184, 21572217, and 21302109) and Institute of Drug Innovation, Chinese Academy of Sciences (CASIMM0420152013 and CASIMM0420151009); Strategic Biological Resources Service Network Program of Chinese Academy of Sciences (ZSTH-001). ; Chinese National Natural Science Foundation [21402184, 21572217, 21302109] ; We gratefully acknowledge financial support from the Chinese National Natural Science Foundation (No. 21402184, 21572217, and 21302109) and Institute of Drug Innovation, Chinese Academy of Sciences (CASIMM0420152013 and CASIMM0420151009); Strategic Biological Resources Service Network Program of Chinese Academy of Sciences (ZSTH-001). ; Chinese National Natural Science Foundation [21402184, 21572217, 21302109] ; Institute of Drug Innovation, Chinese Academy of Sciences [CASIMM0420152013, CASIMM0420151009] ; Institute of Drug Innovation, Chinese Academy of Sciences [CASIMM0420152013, CASIMM0420151009] ; Strategic Biological Resources Service Network Program of Chinese Academy of Sciences [ZSTH-001] ; Strategic Biological Resources Service Network Program of Chinese Academy of Sciences [ZSTH-001] ; We gratefully acknowledge financial support from the Chinese National Natural Science Foundation (No. 21402184, 21572217, and 21302109) and Institute of Drug Innovation, Chinese Academy of Sciences (CASIMM0420152013 and CASIMM0420151009); Strategic Biological Resources Service Network Program of Chinese Academy of Sciences (ZSTH-001). ; Chinese National Natural Science Foundation [21402184, 21572217, 21302109] ; We gratefully acknowledge financial support from the Chinese National Natural Science Foundation (No. 21402184, 21572217, and 21302109) and Institute of Drug Innovation, Chinese Academy of Sciences (CASIMM0420152013 and CASIMM0420151009); Strategic Biological Resources Service Network Program of Chinese Academy of Sciences (ZSTH-001). ; Chinese National Natural Science Foundation [21402184, 21572217, 21302109] ; Institute of Drug Innovation, Chinese Academy of Sciences [CASIMM0420152013, CASIMM0420151009] ; Institute of Drug Innovation, Chinese Academy of Sciences [CASIMM0420152013, CASIMM0420151009] ; Strategic Biological Resources Service Network Program of Chinese Academy of Sciences [ZSTH-001] ; Strategic Biological Resources Service Network Program of Chinese Academy of Sciences [ZSTH-001]
内容类型	期刊论文
源URL	[http://210.75.237.14/handle/351003/29261]
专题	成都生物研究所_天然产物研究
通讯作者	Wei, W (reprint author), Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China.; Zhang, Q (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China.
推荐引用方式 GB/T 7714	Zhang, Q,Wei, W ,Zhang, Q ,et al. Transition-metal-free PhI(OAc)(2)-promoted highly selective hydroboration of terminal alkynes under air[J]. RSC ADVANCES,2017,7(42):26070-26073.
APA	Zhang, Q.,Wei, W .,Zhang, Q .,Wei, W.,Ji, JX.,...&Chen, SY.(2017).Transition-metal-free PhI(OAc)(2)-promoted highly selective hydroboration of terminal alkynes under air.RSC ADVANCES,7(42),26070-26073.
MLA	Zhang, Q,et al."Transition-metal-free PhI(OAc)(2)-promoted highly selective hydroboration of terminal alkynes under air".RSC ADVANCES 7.42(2017):26070-26073.