Asymmetric cyanosilylation of ketones catalyzed by chiral N-oxide-titanium (IV) complex

	Asymmetric cyanosilylation of ketones catalyzed by chiral N-oxide-titanium (IV) complex
	Shen, YC; Feng, XM; Zhang, GL; Jiang, YZ; Feng, XM, Sichuan Univ, Fac Chem, Sichuan Key LGreen Chem & Technol, Chengdu 610064, Peoples R China.
刊名	SYNLETT
	2002
期号	8 页码:1353_1355
关键词	Asymmetric Synthesis Catalysis Cyanohydrins Chiral N-oxides Bifunctional Catalyst
ISSN号	0936-5214
产权排序	3
英文摘要	A new approach for the asymmetric addition of trimethylsilylcyanide to ketones using chiral N-oxide-Ti(iPrO)(4) Complex as catalyst is reported, The screening of a number of chiral N-oxides has resulted in a system that lives the O-TMS ethers of cyanohydrins in good isolated yields with enantiomeric excesses of up to 69%.
学科主题	Chemistry, Organic
语种	英语
WOS记录号	WOS:000177216500039
公开日期	2011-07-08
内容类型	期刊论文
源URL	[http://210.75.237.14/handle/351003/17279]
专题	成都生物研究所_天然产物研究
通讯作者	Feng, XM, Sichuan Univ, Fac Chem, Sichuan Key LGreen Chem & Technol, Chengdu 610064, Peoples R China.
推荐引用方式 GB/T 7714	Shen, YC,Feng, XM,Zhang, GL,et al. Asymmetric cyanosilylation of ketones catalyzed by chiral N-oxide-titanium (IV) complex[J]. SYNLETT,2002(8):1353_1355.
APA	Shen, YC,Feng, XM,Zhang, GL,Jiang, YZ,&Feng, XM, Sichuan Univ, Fac Chem, Sichuan Key LGreen Chem & Technol, Chengdu 610064, Peoples R China..(2002).Asymmetric cyanosilylation of ketones catalyzed by chiral N-oxide-titanium (IV) complex.SYNLETT(8),1353_1355.
MLA	Shen, YC,et al."Asymmetric cyanosilylation of ketones catalyzed by chiral N-oxide-titanium (IV) complex".SYNLETT .8(2002):1353_1355.