Photo-induced ferroelectric switching in perovskite CH3NH3PbI3 films.

	Photo-induced ferroelectric switching in perovskite CH3NH3PbI3 films.
	Wang, Peng; Zhao, Jinjin; Wei, Liyu; Zhu, Qingfeng; Xie, Shuhong; Liu, Jinxi; Meng, Xiangjian; Li, Jiangyu
刊名	NANOSCALE
	2017
文献子类	期刊论文
英文摘要	The photovoltaic conversion efficiency of perovskite solar cells based on organic-inorganic CH3NH3PbI3 has risen spectacularly from 3.8% to over 20% in just seven years, yet quite a few important fundamental issues have not been settled, and the role of spontaneous polarization remains poorly understood. While piezoresponse force microscopy (PFM) has been adopted to probe possible ferroelectricity in CH3NH3PbI3, the reported data are often conflicting and inconclusive, due to the complexity in the apparent piezoresponse and its switching that may arise from ionic motions, electrostatic interactions, and other electromechanical mechanisms. Here, using a combination of microscopic and macroscopic measurements, we unambiguously establish the linear piezoelectricity of CH3NH3PbI3 arising from its spontaneous polarization, which can be switched by an electric field, though other electromechanical contributions such as ionic motions are also shown to exist. More importantly, we demonstrate strong interactions between polarization and light in technologically relevant CH3NH3PbI3 films with good conversion efficiencies, observing that the spontaneous polarization can also be switched by light illumination in the absence of an electric field. The light is shown to reduce the coercive voltage of CH3NH3PbI3 and shifts its nucleation bias, suggesting that the photo-induced switching is caused by ionic motions in combination with a photovoltaic field. This set of studies offer strong evidence on the interactions among photo-induced charges, polarization, and ions in perovskite CH3NH3PbI3, and these fundamental observations lay the ground for answering the technologically important question regarding the effects of ferroelectricity on its photovoltaic conversion.
URL标识	查看原文
语种	英语
内容类型	期刊论文
源URL	[http://ir.siat.ac.cn:8080/handle/172644/12116]
专题	深圳先进技术研究院_医工所
作者单位	NANOSCALE
推荐引用方式 GB/T 7714	Wang, Peng,Zhao, Jinjin,Wei, Liyu,et al. Photo-induced ferroelectric switching in perovskite CH3NH3PbI3 films.[J]. NANOSCALE,2017.
APA	Wang, Peng.,Zhao, Jinjin.,Wei, Liyu.,Zhu, Qingfeng.,Xie, Shuhong.,...&Li, Jiangyu.(2017).Photo-induced ferroelectric switching in perovskite CH3NH3PbI3 films..NANOSCALE.
MLA	Wang, Peng,et al."Photo-induced ferroelectric switching in perovskite CH3NH3PbI3 films.".NANOSCALE (2017).