The study of structural and optical properties of (Eu, La, Sm) codoped ZnO nanoparticles via a chemical route

CORC > 长春光学精密机械与物理研究所 > 中国科学院长春光学精密机械与物理研究所 > 中科院长春光机所知识产出

	The study of structural and optical properties of (Eu, La, Sm) codoped ZnO nanoparticles via a chemical route
	Lang, J.; Q. Zhang; Q. Han; Y. Fang; J. Wang; X. Li; Y. Liu; D. Wang and J. Yang
刊名	Materials Chemistry and Physics
	2017
卷号	194
英文摘要	The (Eu, La, Sm) ions were doped into ZnO nanoparticles by a chemical route, and the substitution of (Eu, La, Sm) for Zn2+ions was proved by analytic techniques of X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman, transmission electron microscope (TEM), photoluminescence (PL) and UVvis absorption spectroscopy. The results revealed that the codoping did not change the wurtzite structure of ZnO nanoparticles, but the diameter of the nanoparticles decreased with increasing the rare earth (RE) doping concentrations. The optical bandgaps calculated through UVvisible absorption spectroscopy were found to decrease from 3.26 to 3.14 eV with increasing the RE doping concentrations, which also proved by the slight shift of UV positions in PL spectra. The sharp red emissions located at 578.2, 590.1 and 615.7 nm were originated from the 4f-4f transitions in Eu3+ions under excitation of 325 nm. And these red emissions of Eu3+ions showed a strong correlation with the energy storage centers of oxygen vacancies in the samples which was introduced by the other RE ions of La3+and Sm3+codoping. 2017 Elsevier B.V.
语种	英语
内容类型	期刊论文
源URL	[http://ir.ciomp.ac.cn/handle/181722/58986]
专题	长春光学精密机械与物理研究所_中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Lang, J.,Q. Zhang,Q. Han,et al. The study of structural and optical properties of (Eu, La, Sm) codoped ZnO nanoparticles via a chemical route[J]. Materials Chemistry and Physics,2017,194.
APA	Lang, J..,Q. Zhang.,Q. Han.,Y. Fang.,J. Wang.,...&D. Wang and J. Yang.(2017).The study of structural and optical properties of (Eu, La, Sm) codoped ZnO nanoparticles via a chemical route.Materials Chemistry and Physics,194.
MLA	Lang, J.,et al."The study of structural and optical properties of (Eu, La, Sm) codoped ZnO nanoparticles via a chemical route".Materials Chemistry and Physics 194(2017).