MoC ultrafine nanoparticles confined in porous graphitic carbon as extremely stable anode materials for lithium- and sodium-ion batteries

doi:10.1039/c6qi00465b

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	MoC ultrafine nanoparticles confined in porous graphitic carbon as extremely stable anode materials for lithium- and sodium-ion batteries
	Li, MC; Yu, SC; Chen, ZH; Wang, ZY; Lv, FC; Nan, B; Zhu, YG; Shi, Y; Wang, WX; Wu, SF
刊名	INORGANIC CHEMISTRY FRONTIERS
	2017
卷号	4 期号:2 页码:289-295
ISSN号	2052-1553
DOI	10.1039/c6qi00465b
文献子类	期刊论文
英文摘要	Molybdenum carbide (MoC)/graphitic carbon nanocomposites are synthesized using a green and facile method. Well-crystallized MoC ultrafine nanoparticles (<5 nm diameter) are formed in situ inside the pores of a highly conductive graphitic carbon matrix. The resulting MoC/graphitic carbon nanocomposites exhibit very promising electrochemical performance when evaluated as anodes in LIBs and SIBs, because the synergistic effects of the small MoC nanoparticles provide fast and efficient transport and porous graphitic carbon can prevent continual rupturing as well as enhance conductivity. Meanwhile, this novel material has potential for broad application in rechargeable batteries, maintaining a reversible capacity of 742 mA h g(-1) after 50 cycles at 200 mA g(-1) for LIBs and a discharge capacity of 250 mA h g(-1) after 50 cycles at 50 mA g(-1) for SIBs. Furthermore, the required Mo can be recovered from wastewater, which gives this method an added environmental benefit and in return satisfy the current demand for sustainable development.
语种	英语
WOS记录号	WOS:000395802300008
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/27385]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式 GB/T 7714	Li, MC,Yu, SC,Chen, ZH,et al. MoC ultrafine nanoparticles confined in porous graphitic carbon as extremely stable anode materials for lithium- and sodium-ion batteries[J]. INORGANIC CHEMISTRY FRONTIERS,2017,4(2):289-295.
APA	Li, MC.,Yu, SC.,Chen, ZH.,Wang, ZY.,Lv, FC.,...&Lu, ZG.(2017).MoC ultrafine nanoparticles confined in porous graphitic carbon as extremely stable anode materials for lithium- and sodium-ion batteries.INORGANIC CHEMISTRY FRONTIERS,4(2),289-295.
MLA	Li, MC,et al."MoC ultrafine nanoparticles confined in porous graphitic carbon as extremely stable anode materials for lithium- and sodium-ion batteries".INORGANIC CHEMISTRY FRONTIERS 4.2(2017):289-295.