Porous, Naturally Derived Hafnium Phytate for the Highly Chemoselective Transfer Hydrogenation of Aldehydes with Other Reducible Moieties

CORC > 化学研究所 > 中国科学院化学研究所 > 其它

	Porous, Naturally Derived Hafnium Phytate for the Highly Chemoselective Transfer Hydrogenation of Aldehydes with Other Reducible Moieties
	Song, Jinliang; Xue, Zhimin; Xie, Chao; Wu, Haoran; Liu, Shuaishuai; Zhang, Lujun; Han, Buxing
刊名	CHEMCATCHEM
	FEB 21 2018
卷号	10 期号:4 页码:725-730
英文摘要	Both the utilization of naturally occurring compounds to prepare functional materials and the selective conversion of aldehydes with other reducible moieties (ORMs) are very attractive topics. Herein, we synthesized a novel porous material, hafnium phytate (Hf-Phy), by using naturally derived sodium phytate as the building block. Hf-Phy has plenty of mesopores centered around 11.8 nm. Hf-Phy showed excellent performance for the transfer hydrogenation of aldehydes with ORMs by using 2-propanol as the hydrogen source with high selectivities (95-100%) for alcohols without reducing ORMs. Systematic studies suggested that the oxophilicity of Hf4+ and the basicity and structure of Hf-Phy contributed significantly to the excellent performance. Additionally, Hf-Phy could be used over at least five cycles without any decrease in activity or selectivity.
WOS记录号	WOS:000425626700008
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/38760]
专题	化学研究所_其它
推荐引用方式 GB/T 7714	Song, Jinliang,Xue, Zhimin,Xie, Chao,et al. Porous, Naturally Derived Hafnium Phytate for the Highly Chemoselective Transfer Hydrogenation of Aldehydes with Other Reducible Moieties[J]. CHEMCATCHEM,FEB ,10(4):725-730.
APA	Song, Jinliang.,Xue, Zhimin.,Xie, Chao.,Wu, Haoran.,Liu, Shuaishuai.,...&Han, Buxing.(FEB ).Porous, Naturally Derived Hafnium Phytate for the Highly Chemoselective Transfer Hydrogenation of Aldehydes with Other Reducible Moieties.CHEMCATCHEM,10(4),725-730.
MLA	Song, Jinliang,et al."Porous, Naturally Derived Hafnium Phytate for the Highly Chemoselective Transfer Hydrogenation of Aldehydes with Other Reducible Moieties".CHEMCATCHEM 10.4(FEB ):725-730.