Controlling Helix Sense at N- and C-Termini in Quinoline Oligoamide Foldamers by beta-Pinene-Derived Pyridyl Moieties | |
Zheng, Lu1; Zhan, Yulin1; Yu, Chengyuan1; Huang, Fu1,2; Wang, Ying1; Jiang, Hua1 | |
刊名 | ORGANIC LETTERS
![]() |
2017-03-17 | |
卷号 | 19期号:6页码:1482-1485 |
英文摘要 | A series of quinoline oligoamide foldamers bearing a beta-pinene-derived pyridyl group at the N-terminus or the C terminus were synthesized, and the efficiencies of chiral inductions have been evaluated by H-1 NMR and CD spectra. The chiral inductions were quantitative when chiral pyridyl acid was appended at the N-terminus, but were inferior when chiral pyridyl amine was appended at the C-terminus. Unexpectedly, N-oxidation on the pyridine ring at the C-terminus does not notably enhance the chiral induction efficiency in spite of the presence of three-center hydrogen bonds. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/38282] ![]() |
专题 | 化学研究所_其它 |
作者单位 | 1.Beijing Normal Univ, Coll Chem, Key Lab Radiopharmaceut, Key Lab Theoret & Computat Photochem, Beijing 100875, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Zheng, Lu,Zhan, Yulin,Yu, Chengyuan,et al. Controlling Helix Sense at N- and C-Termini in Quinoline Oligoamide Foldamers by beta-Pinene-Derived Pyridyl Moieties[J]. ORGANIC LETTERS,2017,19(6):1482-1485. |
APA | Zheng, Lu,Zhan, Yulin,Yu, Chengyuan,Huang, Fu,Wang, Ying,&Jiang, Hua.(2017).Controlling Helix Sense at N- and C-Termini in Quinoline Oligoamide Foldamers by beta-Pinene-Derived Pyridyl Moieties.ORGANIC LETTERS,19(6),1482-1485. |
MLA | Zheng, Lu,et al."Controlling Helix Sense at N- and C-Termini in Quinoline Oligoamide Foldamers by beta-Pinene-Derived Pyridyl Moieties".ORGANIC LETTERS 19.6(2017):1482-1485. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论