Direct Relationship Between Interfacial Microstructure and Confined Crystallization in Poly(Ethylene Oxide)/Silica Composites: The Study of Polymer Molecular Weight Effects | |
Zhao, Weiwei1,2; Su, Yunlan1; Mueller, Alejandro J.3,4,5; Gao, Xia1; Wang, Dujin1 | |
刊名 | JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
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2017-11-01 | |
卷号 | 55期号:21页码:1608-1616 |
关键词 | Confined Crystallization Interphase Nanocomposites Polymer Molecular Weight |
英文摘要 | With particular focus on the characterization of polymer-nanoparticle interaction, the effects of polymer molecular weight (M-n) on confined crystallization of the interfacial region in poly(ethylene oxide) (PEO)/silica (SiO2) composites were investigated, employing differential scanning calorimetry, dynamic light scattering, and proton nuclear magnetic resonance relaxation techniques. Dependence of crystallization on M-n in PEO/SiO2 composites is found to be closely related to the microstructure changes in adsorbed polymer. PEO adsorbs in a manner that produces a tightly bound layer (amorphous) with constant thickness, independent of M-n, and creates a loosely bound layer with flattened structure for short PEO chains but coiled conformation for long chains. The contribution of this M-n-dependent layer to crystallization grows with M-n, showing a transition from non-crystalline phase to the formation of a crystallization peak (-25 to -33 degrees C), and then to crystallization together with non-adsorbed PEO. The comprehensive description of the interfacial region should be a helpful tool in the preparation and modification of polymer nanocomposites. (C) 2017 Wiley Periodicals, Inc. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/41239] ![]() |
专题 | 化学研究所_工程塑料实验室 |
作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Univ Basque Country, UPV EHU, POLYMAT, Fac Chem, Paseo Manuel de Lardizabal 3, Donostia San Sebastian 20018, Spain 4.Univ Basque Country, UPV EHU, Polymer Sci & Technol Dept, Fac Chem, Paseo Manuel de Lardizabal 3, Donostia San Sebastian 20018, Spain 5.Ikerbasque, Basque Fdn Sci, Bilbao, Spain |
推荐引用方式 GB/T 7714 | Zhao, Weiwei,Su, Yunlan,Mueller, Alejandro J.,et al. Direct Relationship Between Interfacial Microstructure and Confined Crystallization in Poly(Ethylene Oxide)/Silica Composites: The Study of Polymer Molecular Weight Effects[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,2017,55(21):1608-1616. |
APA | Zhao, Weiwei,Su, Yunlan,Mueller, Alejandro J.,Gao, Xia,&Wang, Dujin.(2017).Direct Relationship Between Interfacial Microstructure and Confined Crystallization in Poly(Ethylene Oxide)/Silica Composites: The Study of Polymer Molecular Weight Effects.JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,55(21),1608-1616. |
MLA | Zhao, Weiwei,et al."Direct Relationship Between Interfacial Microstructure and Confined Crystallization in Poly(Ethylene Oxide)/Silica Composites: The Study of Polymer Molecular Weight Effects".JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS 55.21(2017):1608-1616. |
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