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Efficient Inverted Organic Solar Cells Based on a Fullerene Derivative-Modified Transparent Cathode
Wang, Yifan1,2; Cong, Hailin1,2; Yu, Bing1,2; Zhang, Zhiguo3,4; Zhan, Xiaowei5
刊名MATERIALS
2017-09-01
卷号10期号:9
关键词Organic Solar Cell (Osc) Cathode Buffer Layer (Cbl) Transparent Conducting Material Fullerene Derivative Zno
英文摘要Indium tin oxide (ITO) is a transparent conductive material which is extensively used in organic solar cells (OSCs) as electrodes. In inverted OSCs, ITO is usually employed as a cathode, which should be modified by cathode buffer layers (CBLs) to achieve better contact with the active layers. In this paper, an amine group functionalized fullerene derivative (DMAPA-C-60) is used as a CBL to modify the transparent cathode ITO in inverted OSCs based on PTB7 as a donor and PC71BM as an acceptor. Compared with traditional ZnO CBL, DMAPA-C-60 exhibited comparable transmittance. OSCs based on DMAPA-C-60 show much better device performance compared with their ZnO counterparts (power conversion efficiencies (PCEs) improved from 6.24 to 7.43%). This is mainly because a better contact between the DMAPA-C-60 modified ITO and the active layer is formed, which leads to better electron transport and collection. Nanoscale morphologies also demonstrate that the surface of DMAPA-C-60-modified ITO is plainer than the ZnO counterparts, which also leads to the better device performance.
语种英语
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/41236]  
专题化学研究所_有机固体实验室
作者单位1.Qingdao Univ, Coll Chem & Chem Engn, Inst Biomed Mat & Engn, Qingdao 266071, Peoples R China
2.Qingdao Univ, Coll Mat Sci & Engn, Growing Base State Key Lab, Lab New Fiber Mat & Modern Text, Qingdao 266071, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing 100190, Peoples R China
5.Peking Univ, Coll Engn, Dept Mat Sci & Engn, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Wang, Yifan,Cong, Hailin,Yu, Bing,et al. Efficient Inverted Organic Solar Cells Based on a Fullerene Derivative-Modified Transparent Cathode[J]. MATERIALS,2017,10(9).
APA Wang, Yifan,Cong, Hailin,Yu, Bing,Zhang, Zhiguo,&Zhan, Xiaowei.(2017).Efficient Inverted Organic Solar Cells Based on a Fullerene Derivative-Modified Transparent Cathode.MATERIALS,10(9).
MLA Wang, Yifan,et al."Efficient Inverted Organic Solar Cells Based on a Fullerene Derivative-Modified Transparent Cathode".MATERIALS 10.9(2017).
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