A general route to coat poly(cyclotriphosphazene-co-4,4 '-sulfonyldiphenol) on various substrates and the derived N, P, S-doped hollow carbon shells for catalysis

CORC > 化学研究所 > 中国科学院化学研究所 > 分子纳米结构与纳米技术实验室

	A general route to coat poly(cyclotriphosphazene-co-4,4 '-sulfonyldiphenol) on various substrates and the derived N, P, S-doped hollow carbon shells for catalysis
	Yang, Shuliang 1,2; Zhu, Yanan 1,2; Cao, Changyan 1,2; Peng, Li 3; Li, Shumu 1; Zhai, Dowei 1,2; Song, Weiguo 1,2
刊名	NANOSCALE
	2017-09-28
卷号	9 期号:36 页码:13538-13545
英文摘要	The construction of core-shell structures through surface coating, and then making use of the synergistic effects between the core and shell to design and synthesize heterogeneous catalysts is a hot topic in the heterogeneous catalysis field. Developing a general coating route with functional shell materials is further highly desirable. Here we found that a poly(cyclotriphosphazene-co-4,4'-sulfonyldiphenol) (PZS) layer can be generally coated on various substrates with different components and morphologies, including metal oxides, noble metal nanoparticles, carbon materials and metal-organic frameworks (MOFs). In addition, the coating thickness could be well controlled through simply adjusting the amount of monomers. Taking advantage of the heteroatoms in the PZS layer and the synergistic effect between the core and shell, new methods for fabrication of co-doped hollow carbon shell catalysts and transition metal phosphide nanoparticles were developed. As a proof-of-concept application, the N, P, S-doped hollow carbon shells prepared by calcination of a ZnCo-ZIFs@PZS core-shell structure could act as a good carbo-catalyst for selective oxidation of C-H bonds in water.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/41113]
专题	化学研究所_分子纳米结构与纳米技术实验室
作者单位	1.Chinese Acad Sci, Inst Chem, Lab Mol Nanostruct & Nanotechnol, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.EPFL ISIC Valais, Inst Chem Sci & Engn, CH-1950 Sion, Switzerland
推荐引用方式 GB/T 7714	Yang, Shuliang,Zhu, Yanan,Cao, Changyan,et al. A general route to coat poly(cyclotriphosphazene-co-4,4 '-sulfonyldiphenol) on various substrates and the derived N, P, S-doped hollow carbon shells for catalysis[J]. NANOSCALE,2017,9(36):13538-13545.
APA	Yang, Shuliang.,Zhu, Yanan.,Cao, Changyan.,Peng, Li.,Li, Shumu.,...&Song, Weiguo.(2017).A general route to coat poly(cyclotriphosphazene-co-4,4 '-sulfonyldiphenol) on various substrates and the derived N, P, S-doped hollow carbon shells for catalysis.NANOSCALE,9(36),13538-13545.
MLA	Yang, Shuliang,et al."A general route to coat poly(cyclotriphosphazene-co-4,4 '-sulfonyldiphenol) on various substrates and the derived N, P, S-doped hollow carbon shells for catalysis".NANOSCALE 9.36(2017):13538-13545.