Molecular conductors from bis(ethylenedithio) tetrathiafulvalene with tris(oxalato)rhodate

	Molecular conductors from bis(ethylenedithio) tetrathiafulvalene with tris(oxalato)rhodate
	Martin, Lee 1; Morritt, Alexander L.1; Lopez, Jordan R.1; Nakazawa, Yasuhiro 2; Akutsu, Hiroki 2; Imajo, Shusaku 2; Ihara, Yoshihiko 3; Zhang, Bin 4,5; Zhang, Yan 6; Guo, Yanjun 7
刊名	DALTON TRANSACTIONS
	2017-08-07
卷号	46 期号:29 页码:9542-9548
英文摘要	This article reports a family of new radical-cation salts of bis(ethylenedithio) tetrathiafulvalene (BEDT-TTF) with tris(oxalato) rhodate: three salts with the formula beta''-(BEDT-TTF)(4)[(cation)Rh(C2O4)(3)]center dot solvent (solvent = fluorobenzene, chlorobenzene, or bromobenzene) and one with the formula pseudo-kappa-(BEDT-TTF)(4)[(NH4)Rh(C2O4)(3)]center dot benzonitrile. We report here the syntheses, crystal structures, electrical properties and Raman spectroscopy of these new molecular conductors. The bromobenzene salt shows a decrease in resistivity below 2.5 K indicative of a superconducting transition and a Shubnikov-de Haas oscillation with a frequency of 232 T and effective mass m* of 1.27m(e).
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/39298]
专题	化学研究所_有机固体实验室
作者单位	1.Nottingham Trent Univ, Sch Sci & Technol, Clifton Lane, Nottingham NG11 8NS, England 2.Osaka Univ, Grad Sch Sci, Dept Chem, 1-1 Machikaneyama Cho, Toyonaka, Osaka 5600043, Japan 3.Hokkaido Univ, Sch Sci, Dept Quantum & Condensed Matter Phys, Kita Ku, Sapporo, Hokkaido 0600810, Japan 4.Chinese Acad Sci, CMS, BNLMS, Organ Solid Lab, Beijing 100190, Peoples R China 5.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 6.Peking Univ, Dept Phys, Inst Condensed Matter & Mat Phys, Beijing 100871, Peoples R China 7.Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Martin, Lee,Morritt, Alexander L.,Lopez, Jordan R.,et al. Molecular conductors from bis(ethylenedithio) tetrathiafulvalene with tris(oxalato)rhodate[J]. DALTON TRANSACTIONS,2017,46(29):9542-9548.
APA	Martin, Lee.,Morritt, Alexander L..,Lopez, Jordan R..,Nakazawa, Yasuhiro.,Akutsu, Hiroki.,...&Guo, Yanjun.(2017).Molecular conductors from bis(ethylenedithio) tetrathiafulvalene with tris(oxalato)rhodate.DALTON TRANSACTIONS,46(29),9542-9548.
MLA	Martin, Lee,et al."Molecular conductors from bis(ethylenedithio) tetrathiafulvalene with tris(oxalato)rhodate".DALTON TRANSACTIONS 46.29(2017):9542-9548.