Multinuclear Phthalocyanine-Fused Molecular Nanoarrays: Synthesis, Spectroscopy, and Semiconducting Property

	Multinuclear Phthalocyanine-Fused Molecular Nanoarrays: Synthesis, Spectroscopy, and Semiconducting Property
	Shang, Hong 1; Xue, Zheng 2; Wang, Kang 1; Liu, Huibiao 2; Jiang, Jianzhuang 1
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2017-06-27
卷号	23 期号:36 页码:8644-8651
关键词	Cyclization Phthalocyanines Self-assembly Semiconductors Zinc
英文摘要	The post-cyclization strategy rather than the conventional ante-cyclotetramerization method was employed for the synthesis of multinuclear phthalocyanine-fused molecular nanoarrays. Reaction of 2,3,9,10,16,17-hexakis(2,6-di-methylphenoxy)-23,24-diaminophthalocyaninato zinc(II) with 2,7-di-tert-butylpyrene-4,5-dione, 2,7-di-tert-butylpyrene-4,5,9,10-tetraone, and hexaketocyclohexane in refluxing acetic acid afforded the corresponding mono-, bi-, and trinuclear phthalocyanine-fused zinc complexes (Pz-pyrene){Zn[Pc(OC8H9)(6)]} (1), (Pz(2)-pyrene){Zn[Pc(OC8H9)(6)]}(2) (2), {(HAT){Zn[Pc(OC8H9)(6)]}(3)} (3) in 46, 13, and 25% yield, respectively, which extend the scope of multinuclear phthalocyanine-fused nanoarrays with different molecular skeletons. The self-assembly behavior of trinuclear phthalocyanine 3 in THF/CH3CN was investigated by electronic absorption spectroscopy and SEM, and the fabricated nanorods showed interesting semiconducting properties, which suggest good application potential of these multinuclear phthalocyanine-fused molecular nanoarrays.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/38897]
专题	化学研究所_有机固体实验室
作者单位	1.Univ Sci & Technol Beijing, Beijing Key Lab Sci & Applicat Funct Mol & Crysta, Dept Chem, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Inst Chem, BNLMS, CAS Key Lab Organ Solids, Beijing 100083, Peoples R China
推荐引用方式 GB/T 7714	Shang, Hong,Xue, Zheng,Wang, Kang,et al. Multinuclear Phthalocyanine-Fused Molecular Nanoarrays: Synthesis, Spectroscopy, and Semiconducting Property[J]. CHEMISTRY-A EUROPEAN JOURNAL,2017,23(36):8644-8651.
APA	Shang, Hong,Xue, Zheng,Wang, Kang,Liu, Huibiao,&Jiang, Jianzhuang.(2017).Multinuclear Phthalocyanine-Fused Molecular Nanoarrays: Synthesis, Spectroscopy, and Semiconducting Property.CHEMISTRY-A EUROPEAN JOURNAL,23(36),8644-8651.
MLA	Shang, Hong,et al."Multinuclear Phthalocyanine-Fused Molecular Nanoarrays: Synthesis, Spectroscopy, and Semiconducting Property".CHEMISTRY-A EUROPEAN JOURNAL 23.36(2017):8644-8651.