Visible-Light-Promoted Asymmetric Cross-Dehydrogenative Coupling of Tertiary Amines to Ketones by Synergistic Multiple Catalysis

	Visible-Light-Promoted Asymmetric Cross-Dehydrogenative Coupling of Tertiary Amines to Ketones by Synergistic Multiple Catalysis
	Yang, Qi 1,2; Zhang, Long 1,2; Ye, Chen 3; Luo, Sanzhong 1,2; Wu, Li-Zhu 3; Tung, Chen-Ho 3
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2017-03-20
卷号	56 期号:13 页码:3694-3698
关键词	Amines Cross-coupling Hydrogen Photochemistry Reaction Mechanisms
英文摘要	Reported herein is an unprecedented photocatalytic asymmetric cross-dehydrogenative coupling reaction between tertiary amines and simple ketones, and it proceeds by synergistic multiple catalysis with substoichiometric amounts of a hydrogen acceptor. This process is enabled by a simple chiral primary amine catalyst through the coupling of a catalytic enamine intermediate and an iminium cation intermediate in situ generated from tetrahydroisoquinoline derivatives by coupled Ru/Co catalysis.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/38250]
专题	化学研究所_分子识别与功能实验室
作者单位	1.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Key Lab Photochem Convers & Optoelect Mat, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Yang, Qi,Zhang, Long,Ye, Chen,et al. Visible-Light-Promoted Asymmetric Cross-Dehydrogenative Coupling of Tertiary Amines to Ketones by Synergistic Multiple Catalysis[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(13):3694-3698.
APA	Yang, Qi,Zhang, Long,Ye, Chen,Luo, Sanzhong,Wu, Li-Zhu,&Tung, Chen-Ho.(2017).Visible-Light-Promoted Asymmetric Cross-Dehydrogenative Coupling of Tertiary Amines to Ketones by Synergistic Multiple Catalysis.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(13),3694-3698.
MLA	Yang, Qi,et al."Visible-Light-Promoted Asymmetric Cross-Dehydrogenative Coupling of Tertiary Amines to Ketones by Synergistic Multiple Catalysis".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.13(2017):3694-3698.