Graphitic Nanocarbon-Selenium Cathode with Favorable Rate Capability for Li-Se Batteries | |
Zhang, Shuai-Feng1,2,3; Wang, Wen-Peng1,2,3; Xin, Sen1,2,3; Ye, Huan1,2,3; Yin, Ya-Xia1,2,3; Guo, Yu-Guo1,2,3 | |
刊名 | ACS APPLIED MATERIALS & INTERFACES
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2017-03-15 | |
卷号 | 9期号:10页码:8759-8765 |
关键词 | Li-se Batteries Graphitic Carbon Se Cathode Chain-like Se Molecules High-rate Capability |
英文摘要 | A well-organized selenium/carbon nanosheets nanocomposite(Se/CNSs) is prepared by confining chain-like Se-n molecules in hierarchically micromesoporous carbon nanosheets. A unique two-dimensional morphology and high graphitization degree of carbon nanosheets benefits fast Li+/e(-) access to the active Se, which guarantees a high utilization of Se during the(de)lithiation process. Besides, the chain-like Se molecules confined in the carbon matrix could alleviate the shuttle effect of polyselenides and promise a stable electrochemistry. Therefore, the resultant Se/CNSs delivers a highly reversible capacity, a long cycle life and favorable rate capabilities. Furthermore, a Li-Se pouch cell built from a metallic Li anode and the as-prepared Se/CNSs cathode exhibits an excellent electrochemical performance, demonstrating the potential of Se/CNSs in serving future energy storage devices with high energy density. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/38212] ![]() |
专题 | 化学研究所_分子纳米结构与纳米技术实验室 |
作者单位 | 1.Chinese Acad Sci, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Shuai-Feng,Wang, Wen-Peng,Xin, Sen,et al. Graphitic Nanocarbon-Selenium Cathode with Favorable Rate Capability for Li-Se Batteries[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(10):8759-8765. |
APA | Zhang, Shuai-Feng,Wang, Wen-Peng,Xin, Sen,Ye, Huan,Yin, Ya-Xia,&Guo, Yu-Guo.(2017).Graphitic Nanocarbon-Selenium Cathode with Favorable Rate Capability for Li-Se Batteries.ACS APPLIED MATERIALS & INTERFACES,9(10),8759-8765. |
MLA | Zhang, Shuai-Feng,et al."Graphitic Nanocarbon-Selenium Cathode with Favorable Rate Capability for Li-Se Batteries".ACS APPLIED MATERIALS & INTERFACES 9.10(2017):8759-8765. |
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