Simultaneous construction of two linkages for the on-surface synthesis of imine-boroxine hybrid covalent organic frameworks

CORC > 化学研究所 > 中国科学院化学研究所 > 分子纳米结构与纳米技术实验室

	Simultaneous construction of two linkages for the on-surface synthesis of imine-boroxine hybrid covalent organic frameworks
	Yue, Jie-Yu 1,2; Mo, Yi-Ping 1,2; Li, Shu-Ying 1,2; Dong, Wei-Long 1,2; Chen, Ting 1; Wang, Dong 1
刊名	CHEMICAL SCIENCE
	2017
卷号	8 期号:3 页码:2169-2174
英文摘要	The orthogonality between the Schiff base reaction and the boronic acid dehydration reaction is explored during the on-surface synthesis process. By activating the above two reactions in one-step and employing asymmetrical substituted monomers and the 3-fold symmetric monomer 1,3,5-tris(4-aminophenyl) benzene (TAPB), highly ordered imine-boroxine hybrid single-layered covalent organic frameworks (sCOFs) have been successfully constructed on HOPG by a gas-solid interface reaction method and characterized by scanning tunnelling microscopy (STM). In particular, the reaction between the meta-substituted monomer and TAPB generates sCOFB with a windmill structure, which is the first sCOF with surface chirality so far reported. The demonstration of the one-step synthesis of multiple linkages to form sCOFs can further enlarge the sCOF family and expand the design routes for functional 2D organic nanomaterials.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/38205]
专题	化学研究所_分子纳米结构与纳米技术实验室
作者单位	1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 2.Univ CAS, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Yue, Jie-Yu,Mo, Yi-Ping,Li, Shu-Ying,et al. Simultaneous construction of two linkages for the on-surface synthesis of imine-boroxine hybrid covalent organic frameworks[J]. CHEMICAL SCIENCE,2017,8(3):2169-2174.
APA	Yue, Jie-Yu,Mo, Yi-Ping,Li, Shu-Ying,Dong, Wei-Long,Chen, Ting,&Wang, Dong.(2017).Simultaneous construction of two linkages for the on-surface synthesis of imine-boroxine hybrid covalent organic frameworks.CHEMICAL SCIENCE,8(3),2169-2174.
MLA	Yue, Jie-Yu,et al."Simultaneous construction of two linkages for the on-surface synthesis of imine-boroxine hybrid covalent organic frameworks".CHEMICAL SCIENCE 8.3(2017):2169-2174.