Synthesis, Structures, and Photophysical Properties of Difuro-Fused Tetrahydro[5]helicene Imide Derivatives
Zhang, Chao1; Li, Meng2; Lu, Hai-Yan1; Chen, Chuan-Feng1,2
刊名ASIAN JOURNAL OF ORGANIC CHEMISTRY
2016-12-01
卷号5期号:12页码:1518-1524
关键词[5]Helicene Aromatic Imide Electrophilic Cyclization Sonogashira Coupling Reactions Suzuki-miyaura Cross-coupling Reactions
英文摘要By using Sonogashira coupling reactions and iodine cyclization reactions, diiodide difuro-fused tetrahydro[5]helicene imides were conveniently synthesized, which then gave a series of functionalized difuro-fused tetrahydro[5]helicene imide derivatives by Suzuki-Miyaura cross-coupling reactions. The crystal structures showed that the aromatic imide dyes had -extended and helical structures, and could pack into herringbone-like architectures. Moreover, the imide dyes also showed intense fluorescence and redshifted emissions in both solution and spin-coated films because of the expanded -conjugation systems and the helical twisted structures.
语种英语
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/38046]  
专题化学研究所_分子识别与功能实验室
作者单位1.Sch Chem & Chem Engn, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
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GB/T 7714
Zhang, Chao,Li, Meng,Lu, Hai-Yan,et al. Synthesis, Structures, and Photophysical Properties of Difuro-Fused Tetrahydro[5]helicene Imide Derivatives[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2016,5(12):1518-1524.
APA Zhang, Chao,Li, Meng,Lu, Hai-Yan,&Chen, Chuan-Feng.(2016).Synthesis, Structures, and Photophysical Properties of Difuro-Fused Tetrahydro[5]helicene Imide Derivatives.ASIAN JOURNAL OF ORGANIC CHEMISTRY,5(12),1518-1524.
MLA Zhang, Chao,et al."Synthesis, Structures, and Photophysical Properties of Difuro-Fused Tetrahydro[5]helicene Imide Derivatives".ASIAN JOURNAL OF ORGANIC CHEMISTRY 5.12(2016):1518-1524.
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