LiMCO3 (M = K, Rb, Cs): a series of mixed alkali carbonates with large birefringence | |
Liu, Q (Liu, Qiong); Li, Z (Li, Zhi); Wang, Y (Wang, Ying); Su, X (Su, Xin); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie) | |
刊名 | DALTON TRANSACTIONS |
2017 | |
卷号 | 46期号:21页码:6894-6899 |
ISSN号 | 1477-9226 |
DOI | 10.1039/c7dt00270j |
英文摘要 | By the hydrothermal method, two new mixed alkali carbonates, LiRbCO3 and LiCsCO3 were synthesized for the first time. Both compounds crystallize in the monoclinic space group P2(1)/n, and exhibit similar wave like [LiCO3](infinity) layers connected by Rb-O and Cs-O bonds, respectively. They not only possess low melt temperature and wide spectral transmittance range, but also have relatively large birefringence confirmed by first principles calculations. In the mixed alkali carbonates system of LiMCO3 (M = K, Rb, Cs), with the increase of atomic radius of the alkali metal, the birefringence is reduced from 0.11 in LiKCO3 to 0.09 in LiCsCO3, while the refractivity is increasing. The increasing refractivity and decreasing birefringence can be interpreted by the enhancement of orbital hybridization resulting from the reduced C-O bond length and weakened structural anisotropy, respectively. |
WOS记录号 | WOS:000402550500010 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/5071] |
专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
通讯作者 | Li, Z (Li, Zhi); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie) |
作者单位 | 1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China 2.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Q ,Li, Z ,Wang, Y ,et al. LiMCO3 (M = K, Rb, Cs): a series of mixed alkali carbonates with large birefringence[J]. DALTON TRANSACTIONS,2017,46(21):6894-6899. |
APA | Liu, Q ,Li, Z ,Wang, Y ,Su, X ,Yang, ZH ,&Pan, SL .(2017).LiMCO3 (M = K, Rb, Cs): a series of mixed alkali carbonates with large birefringence.DALTON TRANSACTIONS,46(21),6894-6899. |
MLA | Liu, Q ,et al."LiMCO3 (M = K, Rb, Cs): a series of mixed alkali carbonates with large birefringence".DALTON TRANSACTIONS 46.21(2017):6894-6899. |
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