Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface | |
Iwamoto, M; Wu, CX; Zhong-can, OY; Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528552, Japan. | |
刊名 | CHEMICAL PHYSICS LETTERS
![]() |
1999 | |
卷号 | 312期号:1页码:7-13 |
关键词 | Maxwell Displacement Current Air Interface Simulation Dynamics Microscopy Films Model |
ISSN号 | 0009-2614 |
英文摘要 | Monolayers of amphiphilic molecules at the liquid-air interface are investigated, taking into account the steric repulsion between molecules and the Coulomb attractive interaction of dipoles with the liquid surface. It is shown that the former favors a perpendicular alignment of molecules at the surface (SmA(p) phase) and the latter gives a tilted orientation (SmCp phase). As the temperature decreases, the competition between these two interactions leads to a second-order phase transition from SmA(p) to SmCp. The large pretransitional fluctuation of the tilt angle at a critical molecular area is predicted. (C) 1999 Elsevier Science B.V. All rights reserved. |
学科主题 | Physics |
URL标识 | 查看原文 |
WOS记录号 | WOS:000083203600002 |
公开日期 | 2012-08-29 |
内容类型 | 期刊论文 |
源URL | [http://ir.itp.ac.cn/handle/311006/13085] ![]() |
专题 | 理论物理研究所_理论物理所1978-2010年知识产出 |
通讯作者 | Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528552, Japan. |
推荐引用方式 GB/T 7714 | Iwamoto, M,Wu, CX,Zhong-can, OY,et al. Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface[J]. CHEMICAL PHYSICS LETTERS,1999,312(1):7-13. |
APA | Iwamoto, M,Wu, CX,Zhong-can, OY,&Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528552, Japan..(1999).Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface.CHEMICAL PHYSICS LETTERS,312(1),7-13. |
MLA | Iwamoto, M,et al."Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface".CHEMICAL PHYSICS LETTERS 312.1(1999):7-13. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论