Magnesium isotopic composition of the oceanic mantle and oceanic Mg cycling
Liu, Ping-Ping1,2,3; Teng, Fang-Zhen4; Dick, Henry J. B.5; Zhou, Mei-Fu6; Chung, Sun-Lin3
刊名GEOCHIMICA ET COSMOCHIMICA ACTA
2017-06-01
卷号206页码:151-165
关键词Abyssal peridotite Magnesium isotope Mantle heterogeneity Magnesium cycling Seafloor alteration
ISSN号0016-7037
DOI10.1016/j.gca.2017.02.016
文献子类Article
英文摘要To constrain the Mg isotopic composition of the oceanic mantle, investigate Mg isotope fractionation of abyssal peridotites during seafloor alteration, and assess Mg budget in the oceans, a suite of 32 abyssal peridotite samples from the Gakkel Ridge and Southwest Indian Ridge (SWIR) was, for the first time, selected for high-precision Mg isotope analyses. Although most of these samples are extensively altered, largely by serpentinization and weathering, primary olivine, diopside and enstatite grains are preserved in some samples. Olivine grains from the least altered samples have delta Mg-26 varying from -0.30 to -0.12 parts per thousand (n = 7), whereas enstatite and diopside have delta Mg-26 varying from -0.27 to -0.16% (n = 7), and from -0.23 to -0.09 parts per thousand (n = 6), respectively. Whole-rock delta Mg-26 values range from -0.24 to 0.03 parts per thousand with an average of -0.12 +/- 0.13% (2SD, n = 32). Strongly serpentinized peridotites have lower average delta Mg-26 values (delta Mg-26 = -0.19 +/- 0.07 parts per thousand, 2SD, n = 7) than weathering-dominated ones (delta Mg-26 = -0.10 +/- 0.12 parts per thousand, 2SD, n = 25). Calculated Mg isotopic compositions of fresh mantle peridotites vary from -0.29 to -0.13 parts per thousand, beyond the previously reported range of the subcontinental lithospheric mantle (-0.25 +/- 0.04 parts per thousand) and the analytical uncertainty (+/- 0.07 parts per thousand, 2SD). Our study therefore indicates that the oceanic mantle may have similar but slightly heterogeneous Mg isotopic compositions to that of subcontinental lithospheric mantle. Secondary serpentinization does not fractionate Mg isotopes of abyssal peridotites, whereas low-T weathering and formation of clay can result in the enrichment of heavy Mg isotopes in abyssal peridotites. This study also demonstrates that fluid-rock interaction does not necessarily produce rocks with intermediate Mg isotopic compositions. Magnesium isotopes of the rocks thereafter are dependent on the secondary minerals formed. We also conclude that the release of light Mg isotopes into the ocean during alteration of abyssal peridotites can be an important influx of Mg for the seawater Mg budget. Abyssal peridotites with a heavy Mg isotopic signature can be recycled into the mantle in subduction zones and may thus result in heterogeneous Mg isotopic compositions of the oceanic mantle and heavy Mg isotopic compositions of arc magmas. (C) 2017 Elsevier Ltd. All rights reserved.
WOS关键词NORTH CHINA CRATON ; PLASMA-MASS SPECTROMETRY ; MID-ATLANTIC RIDGE ; PERIDOTITE XENOLITHS ; ABYSSAL PERIDOTITES ; CARBONATITE METASOMATISM ; GAKKEL RIDGE ; ARCTIC-OCEAN ; THIN CRUST ; FRACTIONATION
WOS研究方向Geochemistry & Geophysics
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000402488000010
资助机构National Science Foundation of China(41473038 ; National Science Foundation of China(41473038 ; China Postdoctoral Science Foundation(2015M570145) ; China Postdoctoral Science Foundation(2015M570145) ; National Science Foundation(EAR-1056713 ; National Science Foundation(EAR-1056713 ; US National Science Foundation(OCE-1434452) ; US National Science Foundation(OCE-1434452) ; (MOST104-2745-M-002-001-ASP) ; (MOST104-2745-M-002-001-ASP) ; 41503010) ; 41503010) ; EAR-1340160) ; EAR-1340160) ; National Science Foundation of China(41473038 ; National Science Foundation of China(41473038 ; China Postdoctoral Science Foundation(2015M570145) ; China Postdoctoral Science Foundation(2015M570145) ; National Science Foundation(EAR-1056713 ; National Science Foundation(EAR-1056713 ; US National Science Foundation(OCE-1434452) ; US National Science Foundation(OCE-1434452) ; (MOST104-2745-M-002-001-ASP) ; (MOST104-2745-M-002-001-ASP) ; 41503010) ; 41503010) ; EAR-1340160) ; EAR-1340160) ; National Science Foundation of China(41473038 ; National Science Foundation of China(41473038 ; China Postdoctoral Science Foundation(2015M570145) ; China Postdoctoral Science Foundation(2015M570145) ; National Science Foundation(EAR-1056713 ; National Science Foundation(EAR-1056713 ; US National Science Foundation(OCE-1434452) ; US National Science Foundation(OCE-1434452) ; (MOST104-2745-M-002-001-ASP) ; (MOST104-2745-M-002-001-ASP) ; 41503010) ; 41503010) ; EAR-1340160) ; EAR-1340160) ; National Science Foundation of China(41473038 ; National Science Foundation of China(41473038 ; China Postdoctoral Science Foundation(2015M570145) ; China Postdoctoral Science Foundation(2015M570145) ; National Science Foundation(EAR-1056713 ; National Science Foundation(EAR-1056713 ; US National Science Foundation(OCE-1434452) ; US National Science Foundation(OCE-1434452) ; (MOST104-2745-M-002-001-ASP) ; (MOST104-2745-M-002-001-ASP) ; 41503010) ; 41503010) ; EAR-1340160) ; EAR-1340160)
内容类型期刊论文
源URL[http://ir.iggcas.ac.cn/handle/132A11/52893]  
专题地质与地球物理研究所_岩石圈演化国家重点实验室
通讯作者Liu, Ping-Ping
作者单位1.Peking Univ, Sch Earth & Space Sci, Key Lab Orogen Belts & Crustal Evolut, Beijing 100871, Peoples R China
2.Chinese Acad Sci, Inst Geol & Geophys, State Key Lab Lithospher Evolut, Beijing 100029, Peoples R China
3.Acad Sinica, Inst Earth Sci, 128 Sec 2,Acad Rd, Taipei 11529, Taiwan
4.Univ Washington, Dept Earth & Space Sci, Isotope Lab, Seattle, WA 98195 USA
5.Woods Hole Oceanog Inst, Dept Geol & Geophys, Woods Hole, MA 02543 USA
6.Univ Hong Kong, Dept Earth Sci, Pokfulam Rd, Hong Kong, Hong Kong, Peoples R China
推荐引用方式
GB/T 7714
Liu, Ping-Ping,Teng, Fang-Zhen,Dick, Henry J. B.,et al. Magnesium isotopic composition of the oceanic mantle and oceanic Mg cycling[J]. GEOCHIMICA ET COSMOCHIMICA ACTA,2017,206:151-165.
APA Liu, Ping-Ping,Teng, Fang-Zhen,Dick, Henry J. B.,Zhou, Mei-Fu,&Chung, Sun-Lin.(2017).Magnesium isotopic composition of the oceanic mantle and oceanic Mg cycling.GEOCHIMICA ET COSMOCHIMICA ACTA,206,151-165.
MLA Liu, Ping-Ping,et al."Magnesium isotopic composition of the oceanic mantle and oceanic Mg cycling".GEOCHIMICA ET COSMOCHIMICA ACTA 206(2017):151-165.
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